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Acid/Base Switching...
Acid/Base Switching of the Tautomerism and Conformation of a Dioxoporphyrin for Integrated Binary Subtraction
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- Ding, Yubin (author)
- East China University of Science and Technology
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- Li, Xin (author)
- KTH,Teoretisk kemi och biologi,Kungliga Tekniska Högskolan (KTH),Royal Institute of Technology (KTH)
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- Hill, Jonathan P. (author)
- National Institute for Materials Science (NIMS)
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- Ariga, Katsuhiko (author)
- National Institute for Materials Science (NIMS)
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- Ågren, Hans (author)
- KTH,Teoretisk kemi och biologi,Kungliga Tekniska Högskolan (KTH),Royal Institute of Technology (KTH)
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- Andreasson, Joakim, 1973 (author)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Zhu, Weihong (author)
- East China University of Science and Technology
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- Tian, He (author)
- East China University of Science and Technology
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- Xie, Yongshu (author)
- East China University of Science and Technology
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(creator_code:org_t)
- 2014-08-14
- 2014
- English.
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In: Chemistry - A European Journal. - : Wiley. - 0947-6539 .- 1521-3765. ; 20:40, s. 12910-12916
- Related links:
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http://dx.doi.org/10...
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- Compared with most of the reported logic devices based on the supramolecular approach, systems based on individual molecules can avoid challenging construction requirements. Herein, a novel dioxoporphyrin DPH22 was synthesized and two of its tautomers were characterized by single-crystal X-ray diffraction studies. Compound DPH22 exhibits multichannel controllable stepwise tautomerization, protonation, and deprotonation processes through interactions with H and F- ions. By using the addition of H+ and F- ions as inputs and UVNis absorption values at.1=412, 510, 562, and 603 nm as outputs, the controlled tautomerism of DPH22 has been successfully used for the construction of an integrated molecular level half-subtractor and comparator. In addition, this acid/base-switched tautomerism is reversible, thus endowing the system with ease of reset and recycling; consequently, there is no need to modulate complicated intermolecular interactions and electron-/chargetransfer processes.
Subject headings
- NATURVETENSKAP -- Kemi -- Teoretisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Theoretical Chemistry (hsv//eng)
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
Keyword
- half-subtractars
- logic gates
- organic electronic
- porphyrinoids
- tautamerism
Publication and Content Type
- ref (subject category)
- art (subject category)
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