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Bidentate phosphine...
Bidentate phosphine ligand based Fe2S2-containing macromolecules : Synthesis, characterization, and catalytic electrochemical hydrogen production
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Gao, Weiming (author)
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Liu, Jianhui (author)
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Akermark, Bjorn (author)
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- Sun, Licheng (author)
- KTH,Organisk kemi
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(creator_code:org_t)
- 2006-10-14
- 2006
- English.
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In: Inorganic Chemistry. - : American Chemical Society (ACS). - 0020-1669 .- 1520-510X. ; 45:23, s. 9169-9171
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- The reaction of [Fe-2(CO)(6)(mu-SCH2)(2)NCH2CH2N(mu-SCH2)(2)Fe-2(CO)(6)] (1) with 1,2-bis(diphenylphosphino) ethane in the presence of Me3NO, 2H(2)O affords two structurally different metallomacromolecules: a dimer of the type [{Fe-2(CO)(5)(mu-SCH2)(2)NCH2CH2N(mu-SCH2) Fe-2(2)(CO)(5)}(Ph2PCH2)(2)] (2) and a tetramer species containing eight iron centers with an overall formula of [{Fe-2(CO)(6)(mu-SCH2)(2)NCH2CH2N( mu-SCH2)(2)Fe-2(CO)(5)}(2)(Ph2PCH2)(2)] (3). Their structures have been determined by X-ray crystallography, showing one macrocyclic complex (2) and one linear complex (3). Electrochemical hydrogen evolution catalyzed by these two complexes with ca. 80-90 single-run turnovers is observed, indicating good potential as catalysts for future applications.
Keyword
- fe-only hydrogenases
- active-site models
- functional models
- evolution
Publication and Content Type
- ref (subject category)
- art (subject category)
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