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A new, dinuclear high spin manganese(III) complex with bridging phenoxy and methoxy groups. Structure and magnetic properties
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- Anderlund, Magnus F. (author)
- Stockholms universitet,Institutionen för organisk kemi
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- Zheng, J. (author)
- Stockholms universitet,Institutionen för organisk kemi
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- Ghiladi, Marten (author)
- Stockholms universitet,Institutionen för organisk kemi
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- Riviere, Eric (author)
- Girerd, Jean-Jacques (author)
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- (creator_code:org_t)
- Elsevier BV, 2006
- 2006
- English.
- In: Inorganic Chemistry Communications. - : Elsevier BV. - 1387-7003 .- 1879-0259. ; 9:12, s. 1195-1198
- Journal article (peer-reviewed)
Abstract
Subject headings
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- A new mu-phenoxy-mu-metoxy di-manganese(III) complex with the trisphenolic ligand, 2,6-bis[((2-hydroxybenzyl)(2-pyridylmethyl)amino)methyl]-4-methylphenol, was isolated as a perchlorate salt. The X-ray structure shows that the two manganese(III) ions are in a distorted octrahedral enviroment with approximately perpendicular Jahn-Teller axes. Investigation of the molar magnetic susceptibility reveals a ferromagnetic coupling between the two high-spin manganese(III) ions. Fitting of the data led to g = 2 and J = 12.5 cm(-1).
Subject headings
- NATURVETENSKAP -- Kemi -- Oorganisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)
Keyword
- manganese complex
- X-ray structure
- magnetic properties
- photosynthetic water oxidation
- photosystem-ii
- phenolate ligands
- tris-bipyridine
- model
- catalysts
- enzymes
- epr
- Inorganic chemistry
Publication and Content Type
- ref (subject category)
- art (subject category)
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- Kritikos, Mikael
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- Åkermark, Björn
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- Royal Institute of Technology
- Stockholm University
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