Search: onr:"swepub:oai:DiVA.org:kth-164452" >
Novel Small Molecul...
-
Cheng, MingDalian Univ Technol, Inst Artificial Photosynth, State Key Lab Fine Chem, DUT KTH Joint Educ & Res Ctr Mol Devices, China
(author)
Novel Small Molecular Materials Based on Phenoxazine Core Unit for Efficient Bulk Heterojunction Organic Solar Cells and Perovskite Solar Cells
- Article/chapterEnglish2015
Publisher, publication year, extent ...
-
2015-02-27
-
American Chemical Society (ACS),2015
-
printrdacarrier
Numbers
-
LIBRIS-ID:oai:DiVA.org:kth-164452
-
https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-164452URI
-
https://doi.org/10.1021/acs.chemmater.5b00001DOI
Supplementary language notes
-
Language:English
-
Summary in:English
Part of subdatabase
Classification
-
Subject category:ref swepub-contenttype
-
Subject category:art swepub-publicationtype
Notes
-
QC 20150423
-
Two novel Acceptor-Donor-Acceptor (A-D-A) structured small molecular (SM-) materials POZ2 and POZ3 using an electron-rich phenoxazine (POZ) unit as a core building block were designed and synthesized. Their unique characteristics, such as suitable energy levels, strong optical absorption in the visible region, high hole mobility, and high conductivity, prompted us to use them both as p-type donor materials (DMs) in SM-bulk heterojunction organic solar cells (BHJ OSCs) and as hole transport materials (HTMs) in CH3NH3PbI3-based perovskite solar cells (PSCs). The POZ(2)-based devices yielded promising power conversion efficiencies (PCEs) of 7.44% and 12.8% in BHJ OSCs and PSCs, respectively, which were higher than the PCEs of 6.73% (BHJ-OSCs) and 11.5% (PSCs) obtained with the POZ3-based devices. Moreover, our results demonstrated that the POZ2 employing the electron-deficient benzothiazole (BTZ) as linker exhibited higher hole mobility and conductivity than that of the POZ3 using thiophene as linker, leading to better device performance both in BHJ-OSCs and PSCs. These results also provide guidance for the molecular design of high charge carrier mobility SM-materials for highly efficient BHJ OSCs and PSCs in the future.
Subject headings and genre
Added entries (persons, corporate bodies, meetings, titles ...)
-
Chen, Cheng
(author)
-
Yang, Xichuan
(author)
-
Huang, JingKTH,Teoretisk kemi och biologi(Swepub:kth)u1yjmndp
(author)
-
Zhang, Fuguo
(author)
-
Xu, Bo
(author)
-
Sun, LichengKTH,Organisk kemi(Swepub:kth)u1umfd9h
(author)
-
Dalian Univ Technol, Inst Artificial Photosynth, State Key Lab Fine Chem, DUT KTH Joint Educ & Res Ctr Mol Devices, ChinaTeoretisk kemi och biologi
(creator_code:org_t)
Related titles
-
In:Chemistry of Materials: American Chemical Society (ACS)27:5, s. 1808-18140897-47561520-5002
Internet link
Find in a library
To the university's database