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Syntheses and cryst...
Syntheses and crystal structures of new palladium(II) and platinum(IV) trialkylsulfonium compounds
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Hess, David (author)
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- Gorlov, Mikhail (author)
- KTH,Oorganisk kemi
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- Fischer, Andreas (author)
- KTH,Oorganisk kemi
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- Kloo, Lars A. (author)
- KTH,Oorganisk kemi
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(creator_code:org_t)
- Wiley, 2007
- 2007
- English.
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In: Zeitschrift für Anorganische und Allgemeines Chemie. - : Wiley. - 0044-2313 .- 1521-3749. ; 633:4, s. 643-646
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- The reactions of platinum(II) iodide with triethyl- or trimethylsulfonium iodide in acetonitrile solution lead to the formation of crystalline products (Et3S)(2)[PtI6] (1) and [Me3S]=[PtI6]center dot CH3CN (2), respectively. The formation of Pt(IV) complexes may be explained either by disproportionation of PtI2 or oxidation by oxygen. Palladium(II) iodide reacts with triethylsulfonium iodide to give the palladium(II) complex (Et3S)(2)[PdI4] (3). The crystal structures of 1-3 were determined by single-crystal X-ray diffraction. In the crystal structures, the compounds 2 and 3 exhibit an extensive hydrogen-bonding network.
Keyword
- platinum
- palladium
- sulfonium
- ionic liquid
- crystal structure
- nanocrystalline solar-cells
- ionic liquids
- electrolytes
- molten
- polyiodides
- complexes
- iodides
- salts
Publication and Content Type
- ref (subject category)
- art (subject category)
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