Investigations of the 2,3 -sigmatropic rearrangements of vinylaziridines and allylic amines

• This account summarizes our studies of [2,3]-sigmatropic rearrangements of vinylaziridines and allylic amines. The scope and limitations of the reactions as well as our present mechanistic understanding are also discussed.

Subject headings

NATURVETENSKAP  -- Kemi (hsv//swe)

NATURAL SCIENCES  -- Chemical Sciences (hsv//eng)

Keyword

rearrangements

vinylaziridines

ylides

pericyclic reactions

asymmetric reactions

enantioselective total-synthesis

ammonium ylides

aza-<2

3>-wittig rearrangements

<2

3>-wittig rearrangement

sigmatropic rearrangement

indolizidine alkaloids

organosulfur compounds

carbon configuration

n-allyl

alcohols

Chemistry

Kemi

Publication and Content Type

ref (subject category)

art (subject category)