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Pentacarbonyl-1 kap...
Pentacarbonyl-1 kappa C-2,2 kappa 3C-(diphenyl-phosphine-1kP)(mu-2-propyl-2-aza-propane-1,3-dithiolato-1 kappa S-2,S ' : 2 kappa S-2,S ')diiron(Fe-Fe)
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Wang, Zhen (author)
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Liu, Jian-Hui (author)
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- Sun, Licheng (author)
- KTH,Organisk kemi
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(creator_code:org_t)
- 2007-06-22
- 2007
- English.
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In: Acta Crystallographica Section E. - : International Union of Crystallography (IUCr). - 1600-5368. ; 63, s. M1959-U1552
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- The title compound, [Fe-2(C5H11NS2)(C12H11P)(CO)(5)], has been prepared and characterized as a model compound of the iron hydrogenase active site through controlled CO ligand displacement of (mu-SCH2)(2)N(CH2CH2CH3)[Fe-2(CO)(6)] with diphenylphosphine. The central Fe2S2 structure is in a butterfly conformation, and each Fe atom displays pseudo-square-pyramidal geometry. The phosphine group occupies an apical position. The propyl group on the bridging N atom is in an equatorial position and takes a zigzag form. In the crystal packing, adjacent pairs of molecules are associated by S center dot center dot center dot S (3.625 angstrom) intermolecular nonbonded weak interactions.
Keyword
- fe-only hydrogenases
- active-site models
Publication and Content Type
- ref (subject category)
- art (subject category)
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