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Fragmentation of mercury compounds under ultraviolet light irradiation
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- Kokkonen, E. (author)
- Univ Oulu, Ctr Mol Mat Res, Oulu 90014, Finland.
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- Loytynoja, Tuomas (author)
- KTH,Teoretisk kemi och biologi,Univ Oulu, Ctr Mol Mat Res, Oulu 90014, Finland.;Royal Inst Technol, Sch Biotechnol, Div Theoret Chem & Biol, S-10691 Stockholm, Sweden.
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- Hautala, L. (author)
- Univ Oulu, Ctr Mol Mat Res, Oulu 90014, Finland.
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- Univ Oulu, Ctr Mol Mat Res, Oulu 90014, Finland Teoretisk kemi och biologi (creator_code:org_t)
- AIP Publishing, 2015
- 2015
- English.
- In: Journal of Chemical Physics. - : AIP Publishing. - 0021-9606 .- 1089-7690. ; 143:7
- Journal article (peer-reviewed)
Abstract
Subject headings
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- Ultraviolet light induced photofragmentation of mercury compounds is studied experimentally with electron energy resolved photoelectron-photoion coincidence techniques and theoretically with computational quantum chemical methods. A high resolution photoelectron spectrum using synchrotron radiation is presented. Fragmentation of the molecule is studied subsequent to ionization to the atomic-mercury-like d orbitals. State dependent fragmentation behaviour is presented and specific reactions for dissociation pathways are given. The fragmentation is found to differ distinctly in similar orbitals of different mercury compounds.
Subject headings
- NATURVETENSKAP -- Fysik -- Atom- och molekylfysik och optik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Atom and Molecular Physics and Optics (hsv//eng)
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- art (subject category)
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