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Patterned Diblock co-polymer Thin Films as Templates for Advanced Anisotropic Metal Nanostructures

Roth, Stephan V. (author)
Santoro, Gonzalo (author)
Risch, Johannes F.H. (author)
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Yu, Shun (author)
Deutsches Elektronen-Synchrotron DESY, Germany
Schwartzkopf, Matthias (author)
Boese, Torsten (author)
Ralph, Döhrmann (author)
Zhang, Peng (author)
Besner, Bastian (author)
Bremer, Philipp (author)
Rukser, Dieter (author)
Rübhausen, Michael A. (author)
Terrill, Nick J. (author)
Staniec, Paul (author)
Yao, Yuan (author)
Metwalli, Ezzeldin (author)
Müller-Buschbaum, Peter (author)
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 (creator_code:org_t)
2015-01-30
2015
English.
In: ACS Applied Materials and Interfaces. - : American Chemical Society (ACS). - 1944-8244 .- 1944-8252. ; 7:23, s. 12470-12477
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • We demonstrate glancing-angle deposition of gold on a nanostructured diblock copolymer, namely polystytene-block-poly(methyl methacrylate) thin film. Exploiting the selective wetting of gold on the polystyrene block, we are able to fabricate directional hierarchical structures. We prove the asymmetric growth of the gold nanoparticles and are able to extract the different growth laws by in situ scattering methods. The optical anisotropy of these hierarchical hybrid materials is further probed by angular resolved spectroscopic methods. This approach enables us to tailor functional hierarchical layers in nanodevices, such as nanoantennae arrays, organic photovoltaics, and sensor electronics.

Subject headings

TEKNIK OCH TEKNOLOGIER  -- Nanoteknik (hsv//swe)
ENGINEERING AND TECHNOLOGY  -- Nano-technology (hsv//eng)

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