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Self-Organized Film...
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Aulin, ChristianKTH,Fiberteknologi
(author)
Self-Organized Films from Cellulose I Nanofibrils Using the Layer-by-Layer Technique
- Article/chapterEnglish2010
Publisher, publication year, extent ...
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2010-03-02
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American Chemical Society (ACS),2010
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printrdacarrier
Numbers
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LIBRIS-ID:oai:DiVA.org:kth-19390
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https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-19390URI
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https://doi.org/10.1021/bm100075eDOI
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https://urn.kb.se/resolve?urn=urn:nbn:se:ri:diva-29567URI
Supplementary language notes
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Language:English
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Summary in:English
Part of subdatabase
Classification
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Subject category:ref swepub-contenttype
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Subject category:art swepub-publicationtype
Notes
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QC 20100525
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cited By 59
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The possibility of forming self-organized films using only charge-stabilized dispersions of cellulose I nanofibrils with opposite charges is presented, that is, the multilayers were composed solely of anionically and cationically modified microfibrillated cellulose (MFC) with a low degree of substitution. The build-up behavior and the properties of the layer-by-layer (LbL)-constructed films were studied using a quartz crystal microbalance with dissipation (QCM-D) and stagnation point adsorption reflectometry (SPAR). The adsorption behavior of cationic/anionic MFC was compared with that of polyethyleneimine (PEI)/anionic MFC. The water contents of five bilayers of cationic/anionic MFC and PEI/anionic MFC were approximately 70 and 50%, respectively. The MFC surface coverage was studied by atomic force microscopy (AFM) measurements, which clearly showed a more dense fibrillar structure in the five bilayer PEI/anionic MFC than in the five bilayer cationic/anionic MFC. The forces between the cellulose-based multilayers were examined using the AFM colloidal probe technique. The forces on approach were characterized by a combination of electrostatic and steric repulsion. The wet adhesive forces were very long-range and were characterized by multiple adhesive events. Surfaces covered by PEU/anionic MFC multilayers required more energy to be separated than surfaces covered by cationic/anionic MFC multilayers.
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Added entries (persons, corporate bodies, meetings, titles ...)
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Johansson, ErikKTH,Fiberteknologi(Swepub:kth)u1unojvn
(author)
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Wågberg, LarsKTH,Fiberteknologi(Swepub:kth)u14jbte3
(author)
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Lindström, TomRISE,Innventia(Swepub:ri)TomLi@ri.se
(author)
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KTHFiberteknologi
(creator_code:org_t)
Related titles
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In:Biomacromolecules: American Chemical Society (ACS)11:4, s. 872-8821525-77971526-4602
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