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Design of Elastomer...
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Målberg, SofiaKTH,Polymerteknologi
(author)
Design of Elastomeric Homo- and Copolymer Networks of Functional Aliphatic Polyester for Use in Biomedical Applications
- Article/chapterEnglish2010
Publisher, publication year, extent ...
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2010-03-25
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American Chemical Society (ACS),2010
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printrdacarrier
Numbers
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LIBRIS-ID:oai:DiVA.org:kth-19409
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https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-19409URI
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https://doi.org/10.1021/cm100520jDOI
Supplementary language notes
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Language:English
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Summary in:English
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Classification
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Subject category:ref swepub-contenttype
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Subject category:art swepub-publicationtype
Notes
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QC 20100525
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An unsaturated aliphatic polyester was synthesized by condensation polymerization to yield the pre-polymer, poly(but-2-ene-1,4-diyl malonate) (PBM), which is applicable as an elastomeric network and as a macroinitiator for the polymerization of cyclic ester monomers. The method of preparation was simple and straightforward with no need to purify the monomers or add a potentially harmful catalyst. The number average molecular weight of the pre-polymer could easily be increased from 5000 to 12000 by extending the reaction time. The pre-polymer PBM was successfully cross-linked with UV-radiation to form a clear, transparent, colorless, flexible, and strong film. PBM as a macroinitiator for L-lactide (LLA) and epsilon-caprolactone (CL) polymerizations highly increased the ductility of the LLA-polymer, while maintaining the strength, compared to PLLA polymerized with common initiators. The tensile properties of PCL were also improved. The linear PCL-PBM and PLLA-PBM polymers were easily cross-linked to give polymers with greater strength and higher modulus as the result.
Subject headings and genre
Added entries (persons, corporate bodies, meetings, titles ...)
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Plikk, PeterKTH,Polymerteknologi(Swepub:kth)u14wk2pu
(author)
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Finne Wistrand, AnnaKTH,Polymerteknologi(Swepub:kth)u17gwfv7
(author)
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Albertsson, Ann-ChristineKTH,Polymerteknologi(Swepub:kth)u1mpsp3u
(author)
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KTHPolymerteknologi
(creator_code:org_t)
Related titles
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In:Chemistry of Materials: American Chemical Society (ACS)22:9, s. 3009-30140897-47561520-5002
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