Silicon Compound Decorated Photoanode for Performance Enhanced Visible Light Driven Water Splitting

• An efficient dye (1) sensitized photoelectrochemical cell (DS-PEC) has been assembled with a silicon compound (3-chloropropyl) trimethoxy-silane (Si-Cl) decorated working electrode (WE) TiO2(1 + 2). The introduction of this Si-Cl molecule on photoanode leads to better performances on efficiency than untreated ones for light driven water splitting. The firm Si-O layer formed on TiO2 increased the resistance of the TiO2/catalyst interface which is assumed to decrease charge recombination from TiO2 to the oxidized catalyst 2. The work presented here provides an effective method to improve the performances of DS-PECs.

Subject headings

NATURVETENSKAP  -- Kemi (hsv//swe)

NATURAL SCIENCES  -- Chemical Sciences (hsv//eng)

Keyword

Dye-sensitized photoelectrochemical cell

photoanode

water splitting

molecular catalyst

Publication and Content Type

ref (subject category)

art (subject category)