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Doppler splitting of in-flight auger decay of dissociating oxygen molecules : The localization of delocalized core holes

Björneholm, O. (author)
Uppsala universitet,Uppsala University,Lund University,Lunds universitet,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Department of Physics,Departments at LTH,Faculty of Engineering, LTH,Björneholm, O., Department of Physics, Uppsala University, Box 530, S-751 21 Uppsala, Sweden
Bässler, M. (author)
Uppsala University,Bässler, M., Department of Physics, Uppsala University, Box 530, S-751 21 Uppsala, Sweden
Ausmees, A. (author)
Uppsala University,Department of Physics, Uppsala University, Box 530, S-751 21 Uppsala, Sweden
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Hjelte, I. (author)
Uppsala University,Department of Physics, Uppsala University, Box 530, S-751 21 Uppsala, Sweden
Feifel, R. (author)
Uppsala University,Department of Physics, Uppsala University, Box 530, S-751 21 Uppsala, Sweden
Wang, H. (author)
Uppsala University,Department of Physics, Uppsala University, Box 530, S-751 21 Uppsala, Sweden
Miron, C. (author)
Uppsala University,Department of Physics, Uppsala University, Box 530, S-751 21 Uppsala, Sweden
Piancastelli, M. N. (author)
Uppsala University,Department of Physics, Uppsala University, Box 530, S-751 21 Uppsala, Sweden, Dept. of Chem. Sci. and Technologies, University Tor Vergata, 00133 Rome, Italy
Svensson, S. (author)
Lund University,Lunds universitet,Uppsala University,Synkrotronljusfysik,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Synchrotron Radiation Research,Department of Physics,Departments at LTH,Faculty of Engineering, LTH,Department of Physics, Uppsala University, Box 530, S-751 21 Uppsala, Sweden,Dept. of Synchrt. Radiation Research, Institute of Physics, Lund University, 5-227 00 Lund, Sweden
Sorensen, S. L. (author)
Gel'mukhanov, Faris (author)
Linköping University,KTH,Bioteknologi
Ågren, Hans (author)
Linköping University,KTH,Bioteknologi
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 (creator_code:org_t)
AMERICAN PHYSICAL SOC, 2000
2000
English.
In: Physical Review Letters. - : AMERICAN PHYSICAL SOC. - 0031-9007 .- 1079-7114. ; 84:13, s. 2826-2829
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • By exploiting the core-excitation-induced dissociation of O-2, we find that the Auger emission exhibits a Doppler-like energy shift. We show this to be a manifestation of localization of the core hole and propose that the problem of core-hole localization versus delocalization in core-hole spectroscopies may be resolved by considering the nature of the measurement.

Keyword

ray raman-scattering
k-edge spectra
auger-spectra
high-resolution
excited states
symmetry
emission
hcl
o2
ionization
NATURAL SCIENCES

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