onr:"swepub:oai:DiVA.org:kth-20390"
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- Cherkasov, A. R. (author)
Correlation analysis in the chemistry of free radicals
- Article/chapterRussian2001
Publisher, publication year, extent ...
- 2001
- printrdacarrier
Numbers
- LIBRIS-ID:oai:DiVA.org:kth-20390
- https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-20390URI
Supplementary language notes
- Language:Russian
- Summary in:Russian
Part of subdatabase
- SwePubSwePub
Classification
Notes
- QC 20100525
- Published data available by now on the use of correlation analysis in the free-radical chemistry are discussed systematically. The scales of <> sigma -constants of substituents proposed previously are analysed. It is shown that none of them is suitable as a general scale because almost in all cases, it is impossible to separate correctly the proper radical and polar contributions to the overall effect of substituents. A new approach to the quantitative estimation of the relationship between the structure and reactivity of molecules in free-radical processes is proposed and called r(-2)-analysis.
Subject headings and genre
- bond-dissociation energies
- hyperfine coupling-constants
- carbon-centered radicals
- benzyl-type radicals
- inductive electronegativity scale
- electron reduction potentials
- substituted methyl radicals
- cis-trans isomerization
- tert-butoxy radicals
- delta-d scale
Added entries (persons, corporate bodies, meetings, titles ...)
- Jonsson, Mats.KTH,Kemi(Swepub:kth)u11mc94v (author)
- Galkin, V. I. (author)
- Cherkasov, R. A. (author)
- KTHKemi (creator_code:org_t)
Related titles
- In:Uspehi himii70:1, s. 3-270042-13081817-5651
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- Cherkasov, A. R.
- Jonsson, Mats.
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- Cherkasov, R. A.
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- Royal Institute of Technology
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