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LiF-MgF2 composite ...
LiF-MgF2 composite electrolyte for advanced ceramic fuel cells : structure, electrical properties and applications
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- Zhu, Bin (author)
- KTH,Kemiteknik
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Fu, Q. X. (author)
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Meng, G. Y. (author)
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Jurado, J. F. (author)
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- Albinsson, Ingvar, 1962 (author)
- Gothenburg University,Göteborgs universitet,Institutionen för fysik (GU),Department of Physics (GU)
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Mellander, B. E. (author)
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(creator_code:org_t)
- 2002
- 2002
- English.
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In: Solid State Ionics. - 0167-2738 .- 1872-7689. ; 148:04-mar, s. 583-589
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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https://gup.ub.gu.se...
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Abstract
Subject headings
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- The two-phase composite, LiF-MgF2, has been discovered to have high ionic conductivity within a wide composition range, e.g., 10(-2)-10(-1) S cm(-1) at 600-800 degreesC, which is several orders of magnitude higher than that of pure LiF or MgF2. In addition, the activation energy of the composite is much lower than that of the pure phases. The remarkable conductivity enhancement as well as the low activation energy is attributed to the composite effect, i.e., the conduction takes place mainly in the interfacial region between LiF and MgF2 grains. The agreements of conductivity derived from two different methods, impedance spectra and fuel cell characterisation, in combination of the ESR results, show a possibility that proton (plus hydride ion) conduction dominates the electrical conduction in the LiF-MgF2 system under the H-2/air fuel cell environments.
Subject headings
- NATURVETENSKAP -- Fysik -- Den kondenserade materiens fysik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Condensed Matter Physics (hsv//eng)
Keyword
- fluorides
- composite electrolyte
- proton
- hydride ion
- fuel cell
- technology
- system
- phase
- na
- Composite electrolyte
- Fluorides
- Fuel cell
- Hydride ion
- Proton
Publication and Content Type
- ref (subject category)
- art (subject category)
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