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The structure of th...
The structure of the new compound YBaCo4O7 with a magnetic feature
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Valldor, M. (author)
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- Andersson, Magnus (author)
- KTH,Mikroelektronik och informationsteknik, IMIT
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(creator_code:org_t)
- 2002
- 2002
- English.
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In: Solid State Sciences. - 1293-2558 .- 1873-3085. ; 4:7, s. 923-931
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
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- Single crystals and pure powder samples of the new compound YBaCo4O7 have been obtained by solid-state reactions, using different temperature programs. From X-ray powder diffraction the structure was determined as hexagonal, space group P6(3)mc. having the cell parameters a = 6.2982(4) and c = 10.2467(9) Angstrom. This phase is isostructural with that previously reported for LuBaZn3.09Al0.91O7. Refinements of powder neutron diffraction data collected at two different temperatures and X-ray single crystal data at room temperature, agree well. Changes with temperature in the relative positions of Co and its surrounding oxygen atoms are the only geometrical manifestation of a probable spin-glass transition at about 65 K from the high temperature paramagnetic state.
Keyword
- cobalt oxides
- geometrical frustration
- single crystal XRD
- NPD
- neutron-diffraction
- crystal-structure
- x-ray
- oxides
- ho
- dy
- gd
- eu
- sm
Publication and Content Type
- ref (subject category)
- art (subject category)
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