Search: onr:"swepub:oai:DiVA.org:kth-22093" >
Light-driven tyrosi...
Light-driven tyrosine radical formation in a ruthenium-tyrosine complex attached to nanoparticle TiO2
-
- Ghanem, Raed (author)
- Lund University,Lunds universitet,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
-
Xu, Y. H. (author)
-
- Pan, Jie (author)
- Lund University,Lunds universitet,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
-
show more...
-
Hoffmann, T. (author)
-
- Andersson, Johan (author)
- Lund University,Lunds universitet,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
-
- Polivka, Tomas (author)
- Lund University,Lunds universitet,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
-
- Pascher, Torbjörn (author)
- Lund University,Lunds universitet,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
-
- Styring, Stenbjörn (author)
- Lund University,Lunds universitet,Biokemi och Strukturbiologi,Centrum för Molekylär Proteinvetenskap,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Biochemistry and Structural Biology,Center for Molecular Protein Science,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
-
Sun, Licheng C. (author)
-
- Sundström, Villy (author)
- Lund University,Lunds universitet,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
-
show less...
-
(creator_code:org_t)
- 2002-10-29
- 2002
- English.
-
In: Inorganic Chemistry. - : American Chemical Society (ACS). - 0020-1669 .- 1520-510X. ; 41:24, s. 6258-6266
- Related links:
-
http://dx.doi.org/10...
-
show more...
-
https://urn.kb.se/re...
-
https://doi.org/10.1...
-
https://lup.lub.lu.s...
-
show less...
Abstract
Subject headings
Close
- We demonstrate a possibility of multistep electron transfer in a supramolecular complex adsorbed on the surface of nanocrystalline TiO2. The complex mimics the function of the tyrosinez and chlorophyll unit P-680 in natural photosystem II (PSII). A ruthenium(II) tris(bipyridyl) complex covalently linked to a L-tyrosine ethyl ester through an amide bond was attached to the surface of nanocrystalline TiO2 via carboxylic acid groups linked to the bpy ligands. Synthesis and characterization of this complex are described. Excitation (450 nm) of the complex promotes an electron to a metal-to-ligand charge-transfer (MLCT) excited state, from which the electron is injected into TiO2. The photogeneration of Ru(III) is followed by an intramolecular electron transfer from tyrosine to Ru(III), regenerating the photosensitizer Ru(II) and forming the tyrosyl radical. The tyrosyl radical is formed in less than 5 us with a yield of 15%. This rather low yield is a result of a fast back electron transfer reaction from the nanocrystalline TiO2 to the photogenerated Ru(III).
Subject headings
- NATURVETENSKAP -- Biologi (hsv//swe)
- NATURAL SCIENCES -- Biological Sciences (hsv//eng)
Keyword
- photosynthetic oxygen evolution
- photosystem-ii
- artificial photosynthesis
- electron-transfer
- water oxidation
- colloidal tio2
- y-z
- system
- model
- luminescence
Publication and Content Type
- ref (subject category)
- art (subject category)
Find in a library
To the university's database
- By the author/editor
-
Ghanem, Raed
-
Xu, Y. H.
-
Pan, Jie
-
Hoffmann, T.
-
Andersson, Johan
-
Polivka, Tomas
-
show more...
-
Pascher, Torbjör ...
-
Styring, Stenbjö ...
-
Sun, Licheng C.
-
Sundström, Villy
-
show less...
- About the subject
-
- NATURAL SCIENCES
-
NATURAL SCIENCES
-
and Biological Scien ...
- Articles in the publication
-
Inorganic Chemis ...
- By the university
-
Royal Institute of Technology
-
Lund University