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A study of the inner-valence ionization region in HCl and DCl

Burmeister, F. (author)
Andersson, L. Mauritz (author)
Ohrwall, G. (author)
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Richter, T. (author)
Zimmermann, P. (author)
Godehusen, K. (author)
Martins, M. (author)
Karlsson, H O (author)
Sorensen, S. L. (author)
Bjorneholm, O. (author)
Feifel, R. (author)
Wiesner, K. (author)
Goscinski, O. (author)
Karlsson, L. (author)
Svensson, S. (author)
Yencha, A. J. (author)
Ristinmaa Sörensen, Stacey (author)
Lund University,Lunds universitet,Synkrotronljusfysik,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Synchrotron Radiation Research,Department of Physics,Departments at LTH,Faculty of Engineering, LTH
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 (creator_code:org_t)
2004-03-02
2004
English.
In: Journal of Physics B. - : IOP Publishing. - 0953-4075 .- 1361-6455. ; 37:6, s. 1173-1183
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • An in-depth photoionization study of the inner-valence electrons in HCl and DCl has been performed using synchrotron radiation. A series of photoelectron spectra of HCl were obtained at a resolution of 23 meV over the binding energy range 25-30.5 eV at various excitation energies and at two different electron collection angles relative to the plane of polarization of the undulator radiation. In addition, photoelectron spectra of DCl were recorded at two different excitation energies. These spectra were compared directly with the threshold photoelectron spectra of HCl and DCl that were recorded previously under similar resolution conditions (similar to30 meV). This comparative study reveals new information on the nature of the numerous band systems observed in this binding energy region. In addition, we present the experimental confirmation of the theoretical prediction given by Andersson et al (2001 Phys. Rev. A 65 012705) that a vibrational progression showing interference structure would appear in the main inner-valence ionization band in the photoelectron spectrum of DCl at a resolution of 10 meV.

Subject headings

NATURVETENSKAP  -- Fysik -- Atom- och molekylfysik och optik (hsv//swe)
NATURAL SCIENCES  -- Physical Sciences -- Atom and Molecular Physics and Optics (hsv//eng)

Keyword

threshold photoelectron-spectroscopy
coincidence spectroscopy
photoionization
chloride
spectrum

Publication and Content Type

ref (subject category)
art (subject category)

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