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Redox Catalysis Fac...
Redox Catalysis Facilitates Lignin Depolymerization
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- Bosque, Irene (author)
- Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, Michigan 48109, United States
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- Magallanes, Gabriel (author)
- Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, Michigan 48109, United States
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- Rigoulet, Mathilde (author)
- Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, Michigan 48109, United States
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- Kärkäs, Markus D. (author)
- Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, Michigan 48109, United States
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- Stephenson, Corey R. J. (author)
- Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, Michigan 48109, United States
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(creator_code:org_t)
- 2017-06-07
- 2017
- English.
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In: ACS Central Science. - : American Chemical Society (ACS). - 2374-7951 .- 2374-7943. ; 3:6, s. 621-628
- Related links:
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https://doi.org/10.1...
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https://pubs.acs.org...
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https://urn.kb.se/re...
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Abstract
Subject headings
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- Lignin is a recalcitrant and underexploited natural feedstock for aromatic commodity chemicals, and its degradation generally requires the use of high temperatures and harsh reaction conditions. Herein we present an ambient temperature one-pot process for the controlled oxidation and depolymerization of this potent resource. Harnessing the potential of electrocatalytic oxidation in conjugation with our photocatalytic cleavage methodology, we have developed an operationally simple procedure for selective fragmentation of β-O-4 bonds with excellent mass recovery, which provides a unique opportunity to expand the existing lignin usage from energy source to commodity chemicals and synthetic building block source.
Subject headings
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
Keyword
- Kemi
- Chemistry
Publication and Content Type
- ref (subject category)
- art (subject category)
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