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Influence of termin...
Influence of terminal acryloyl arms on the coordination chemistry of a ditopic pyrimidine-hydrazone ligand : comparison of Pb(II), Zn(II), Cu(II), and Ag(I) complexes
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- Hutchinson, Daniel J. (author)
- Department of Chemistry, University of Otago
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- Hanton, Lyall R. (author)
- Department of Chemistry, University of Otago
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- Moratti, S. C. (author)
- Department of Chemistry, University of Otago
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(creator_code:org_t)
- 2013-02-20
- 2013
- English.
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In: Inorganic Chemistry. - : American Chemical Society (ACS). - 0020-1669 .- 1520-510X. ; 52:5, s. 2716-28
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
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- A new ditopic pyrimidine-hydrazone ligand, 6-hydroxymethylacryloyl-2-pyridinecarboxaldehyde, 2,2'-[2,2'-(2-methyl-4,6-pyrimidinediyl)bis(1-methylhydrazone)] (L2), was synthesized with terminal acryloyl functional groups to allow incorporation into copolymer gel actuators. NMR spectroscopy was used to show that L2 adopted a horseshoe shape with transoid-transoid pym-hyz-py linkages. Metal complexation studies were performed with L2 and salts of Pb(II), Zn(II), Cu(II), and Ag(I) ions in CH3CN in a variety of metal to ligand ratios. Reacting L2 with an excess amount of any of the metal ions resulted in linear complexes where the pym-hyz-py linkages were rotated to a cisoid-cisoid conformation. NMR spectroscopy showed that the acryloyl arms of L2 did not interact with the bound metal ions in solution. Seven of the linear complexes (1-7) were crystallized and analyzed by X-ray diffraction. Most of these complexes (4-7) also showed no coordination between the acryloyl arms and the metal ions; however, complexes 1-3 showed some interactions. Both of the acryloyl arms were coordinated to Pb(II) ions in [Pb2L2(SO3CF3)4] (1), one through the carbonyl oxygen donor and the other through the alkoxy oxygen donor. One of the acryloyl arms of [Cu2L2(CH3CN)3](SO3CF3)4 (2) was coordinated to one of the Cu(II) ions through the carbonyl oxygen donor. There appeared to be a weak association between the alkoxy donors of the acryloyl arms and the Pb(II) ions of [Pb2L2(ClO4)4].CH3CN (3). Reaction of excess AgSO3CF3 with L2 was repeated in CD3NO2, resulting in crystals of {[Ag7(L2)2(SO3CF3)6(H2O)2] SO3CF3}infinity (8), the polymeric structure of which resulted from coordination between the carbonyl donors of the acryloyl arms and the Ag(I) ions. In all cases the coordination and steric effects of the acryloyl arms did not inhibit isomerization of the pym-hyz bonds of L2 or the core shape of the linear complexes.
Subject headings
- NATURVETENSKAP -- Kemi -- Oorganisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)
Keyword
- Copper/chemistry
- Crystallography
- X-Ray
- Hydrazones/*chemistry
- Lead/chemistry
- Ligands
- Models
- Molecular
- Molecular Structure
- Organometallic Compounds/chemical synthesis/*chemistry
- Pyrimidines/*chemistry
- Silver/chemistry
- Zinc/chemistry
Publication and Content Type
- ref (subject category)
- art (subject category)
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