Search: onr:"swepub:oai:DiVA.org:kth-26366" > Dissociative recomb...
Fältnamn | Indikatorer | Metadata |
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000 | 05470naa a2200757 4500 | |
001 | oai:DiVA.org:kth-26366 | |
003 | SwePub | |
008 | 101124s2004 | |||||||||||000 ||eng| | |
009 | oai:research.chalmers.se:0f025fe8-62c8-4f3b-8acd-b2ca5d93a049 | |
009 | oai:gup.ub.gu.se/53725 | |
024 | 7 | a https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-263662 URI |
024 | 7 | a https://doi.org/10.1063/1.16693882 DOI |
024 | 7 | a https://research.chalmers.se/publication/537252 URI |
024 | 7 | a https://gup.ub.gu.se/publication/537252 URI |
040 | a (SwePub)kthd (SwePub)cthd (SwePub)gu | |
041 | a engb eng | |
042 | 9 SwePub | |
072 | 7 | a ref2 swepub-contenttype |
072 | 7 | a art2 swepub-publicationtype |
100 | 1 | a Öjekull, Jenny,d 1973u Gothenburg University,Göteborgs universitet,Institutionen för kemi,Department of Chemistry4 aut0 (Swepub:gu)xojeje |
245 | 1 0 | a Dissociative recombination of NH4+ and ND4+ ions :b Storage ring experiments and ab initio molecular dynamics |
264 | 1 | b AIP Publishing,c 2004 |
338 | a print2 rdacarrier | |
500 | a QC 20101124 | |
520 | a The dissociative recombination (DR) process of NH4+ and ND4+ molecular ions with free electrons has been studied at the heavy-ion storage ring CRYRING (Manne Siegbahn Laboratory, Stockholm University). The absolute cross sections for DR of NH4+ and ND4+ in the collision energy range 0.001-1 eV are reported, and thermal rate coefficients for the temperature interval from 10 to 2000 K are calculated from the experimental data. The absolute cross section for NH4+ agrees well with earlier work and is about a factor of 2 larger than the cross section for ND4+. The dissociative recombination of NH4+ is dominated by the product channels NH3+H (0.85+/-0.04) and NH2+2H (0.13+/-0.01), while the DR of ND4+ mainly results in ND3+D (0.94+/-0.03). Ab initio direct dynamics simulations, based on the assumption that the dissociation dynamics is governed by the neutral ground-state potential energy surface, suggest that the primary product formed in the DR process is NH3+H. The ejection of the H atom is direct and leaves the NH3 molecule highly vibrationally excited. A fraction of the excited ammonia molecules may subsequently undergo secondary fragmentation forming NH2+H. It is concluded that the model results are consistent with gross features of the experimental results, including the sensitivity of the branching ratio for the three-body channel NH2+2H to isotopic exchange. | |
650 | 7 | a NATURVETENSKAPx Fysik0 (SwePub)1032 hsv//swe |
650 | 7 | a NATURAL SCIENCESx Physical Sciences0 (SwePub)1032 hsv//eng |
650 | 7 | a NATURVETENSKAPx Kemix Fysikalisk kemi0 (SwePub)104022 hsv//swe |
650 | 7 | a NATURAL SCIENCESx Chemical Sciencesx Physical Chemistry0 (SwePub)104022 hsv//eng |
653 | a Ammonia | |
653 | a Computer simulation | |
653 | a Dissociation | |
653 | a Energy transfer | |
653 | a Ion exchange | |
653 | a Ionization | |
653 | a Isotopes | |
653 | a Mathematical models | |
653 | a Molecular vibrations | |
653 | a Positive ions | |
653 | a Potential energy | |
653 | a Probability | |
653 | a Storage rings | |
653 | a Thermal effects | |
653 | a Physics | |
653 | a Fysik | |
700 | 1 | a Andersson, Patrik U,d 1970u Gothenburg University,Göteborgs universitet,Institutionen för kemi,Department of Chemistry4 aut0 (Swepub:gu)xandpa |
700 | 1 | a Någård, M. B.u Gothenburg University,Göteborgs universitet,Institutionen för kemi,Department of Chemistry4 aut |
700 | 1 | a Pettersson, Jan B. C.,d 1962u Gothenburg University,Göteborgs universitet,Institutionen för kemi,Department of Chemistry4 aut0 (Swepub:gu)xpettj |
700 | 1 | a Derkatch, Aliku Alba Nova Universitetscentrum,AlbaNova University Center. Stockholm Center for Physics, Astronomy and Biotechnology4 aut0 (Swepub:kth)u14h2kw1 |
700 | 1 | a Neau, A.u Alba Nova Universitetscentrum,AlbaNova University Center. Stockholm Center for Physics, Astronomy and Biotechnology4 aut |
700 | 1 | a Rosén, S.u Alba Nova Universitetscentrum,AlbaNova University Center. Stockholm Center for Physics, Astronomy and Biotechnology4 aut |
700 | 1 | a Thomas, R.u Alba Nova Universitetscentrum,AlbaNova University Center. Stockholm Center for Physics, Astronomy and Biotechnology4 aut |
700 | 1 | a Larsson, M.u Alba Nova Universitetscentrum,AlbaNova University Center. Stockholm Center for Physics, Astronomy and Biotechnology4 aut |
700 | 1 | a Österdahl, Fabianu KTH,Fysik,Kungliga Tekniska Högskolan (KTH),Royal Institute of Technology (KTH)4 aut0 (Swepub:kth)u1er6waw |
700 | 1 | a Semaniak, J.u Akademia Swietokrzyska im. Jana Kochanowskiego w Kielcach4 aut |
700 | 1 | a Danared, Håkan4 aut0 (Swepub:kth)u1jryotr |
700 | 1 | a Källberg, A.4 aut |
700 | 1 | a af Ugglas, M.4 aut |
700 | 1 | a Markovic, Nikola,d 1961u Chalmers tekniska högskola,Chalmers University of Technology4 aut0 (Swepub:cth)nikola |
710 | 2 | a Göteborgs universitetb Institutionen för kemi4 org |
773 | 0 | t Journal of Chemical Physicsd : AIP Publishingg 120:16, s. 7391-7399q 120:16<7391-7399x 0021-9606x 1089-7690 |
856 | 4 | u http://dx.doi.org/10.1063/1.1669388y FULLTEXT |
856 | 4 8 | u https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-26366 |
856 | 4 8 | u https://doi.org/10.1063/1.1669388 |
856 | 4 8 | u https://research.chalmers.se/publication/53725 |
856 | 4 8 | u https://gup.ub.gu.se/publication/53725 |
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