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Mild and Versatile Functionalization of Nacre-Mimetic Cellulose Nanofibrils/Clay Nanocomposites by Organocatalytic Surface Engineering

Alimohammadzadeh, Rana (author)
Mittuniversitetet,Institutionen för naturvetenskap
Medina, Lilian (author)
KTH,Biokompositer
Deiana, Luca (author)
Mittuniversitetet,Institutionen för naturvetenskap
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Berglund, Lars, 1956- (author)
KTH,VinnExcellens Centrum BiMaC Innovation,Biokompositer,Wallenberg Wood Science Center
Cordova, Armando, 1970- (author)
Mittuniversitetet,Institutionen för naturvetenskap
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 (creator_code:org_t)
2020-06-29
2020
English.
In: ACS Omega. - : American Chemical Society (ACS). - 2470-1343. ; 5:31, s. 19363-19370
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • Development of surface-engineering strategies, which are facile, versatile, and mild, are highly desirable in tailor-made functionalization of high-performance bioinspired nanocomposites. We herein disclose for the first time a general organocatalytic strategy for the functionalization and hydrophobization of nacre-mimetic nanocomposites, which includes vide supra key aspects of surface engineering. The merging of metal-free catalysis and the design of nacre-mimetic nanocomposite materials were demonstrated by the organocatalytic surface engineering of cellulose nanofibrils/clay nanocomposites providing the corresponding bioinspired nanocomposites with good mechanical properties, hydrophobicity, and useful thia-, amino, and olefinic functionalities.

Subject headings

TEKNIK OCH TEKNOLOGIER  -- Kemiteknik -- Polymerteknologi (hsv//swe)
ENGINEERING AND TECHNOLOGY  -- Chemical Engineering -- Polymer Technologies (hsv//eng)
NATURVETENSKAP  -- Kemi (hsv//swe)
NATURAL SCIENCES  -- Chemical Sciences (hsv//eng)

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