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The effect of neutr...
The effect of neutralizing agent on the synthesis and characterization of Mn3O4 nanoparticles
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Durmus, Z. (author)
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Tomas, M. (author)
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Baykal, A. (author)
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Kavas, H. (author)
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Altincekic, T. Gurkaynak (author)
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- Toprak, Muhammet S. (author)
- KTH,Funktionella material, FNM
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(creator_code:org_t)
- 2010
- 2010
- English.
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In: Russian Journal of Inorganic Chemistry. - 0036-0236 .- 1531-8613. ; 55:12, s. 1947-1952
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- We report on the synthesis of Mn3O4 nanoparticles via a two-step hydrothermal route by using Mn(CH3COO)(2) as the only starting material and TMAOH and NaOH as hydrolysing agents. XRD and FT-IR analyses confirmed the composition and structure of Mn3O4. TEM images showed that spheroid Mn3O4 nanostructures obtained by this method have average particle size of 6 and 14 nm for NaOH and TMAOH hydrolyzed samples respectively. Particle size analysis indicated a strong aggregation of nanoparticles and exhibited bi-modal distribution with average size of aggregates as similar to 250 nm and 1.1 mu m for both samples. Zeta potential analysis revealed adsorbed TMAOH species on the surface of Mn3O4 nanoparticles hydrolyzed using TMAOH. ESR analyses resulted in broader lines and smaller g values than bulk Mn3O4 nanoparticles, probably due to the exchange-coupled system with unlike spins such as canted spin at surface of high-surface-disordered nanoparticles.
Subject headings
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Keyword
- LOW-TEMPERATURE SYNTHESIS
- CATALYTIC COMBUSTION
- MANGANESE OXIDE
- OXIDATION
- NANOCRYSTALS
- HAUSMANNITE
- ROUTE
- CO3O4
- Chemistry
- Kemi
Publication and Content Type
- ref (subject category)
- art (subject category)
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