The effect of neutralizing agent on the synthesis and characterization of Mn3O4 nanoparticles

Durmus, Z. (author)

Tomas, M. (author)

Baykal, A. (author)

Kavas, H. (author)

Altincekic, T. Gurkaynak (author)

(creator_code:org_t)

2010
2010
English.
In: Russian Journal of Inorganic Chemistry. - 0036-0236 .- 1531-8613. ; 55:12, s. 1947-1952

Related links:: https://urn.kb.se/re...; show more...; https://doi.org/10.1...; show less...

Abstract Subject headings

We report on the synthesis of Mn3O4 nanoparticles via a two-step hydrothermal route by using Mn(CH3COO)(2) as the only starting material and TMAOH and NaOH as hydrolysing agents. XRD and FT-IR analyses confirmed the composition and structure of Mn3O4. TEM images showed that spheroid Mn3O4 nanostructures obtained by this method have average particle size of 6 and 14 nm for NaOH and TMAOH hydrolyzed samples respectively. Particle size analysis indicated a strong aggregation of nanoparticles and exhibited bi-modal distribution with average size of aggregates as similar to 250 nm and 1.1 mu m for both samples. Zeta potential analysis revealed adsorbed TMAOH species on the surface of Mn3O4 nanoparticles hydrolyzed using TMAOH. ESR analyses resulted in broader lines and smaller g values than bulk Mn3O4 nanoparticles, probably due to the exchange-coupled system with unlike spins such as canted spin at surface of high-surface-disordered nanoparticles.

By the author/editor: Durmus, Z.; Tomas, M.; Baykal, A.; Kavas, H.; Altincekic, T. G ...; Toprak, Muhammet ...

About the subject

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