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A comparison between micro- and nanocellulose-filled composite adhesives for oil paintings restoration

Cataldi, A. (author)
Berglund, Lars, 1956- (author)
KTH,Fiber- och polymerteknologi
Deflorian, F. (author)
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Pegoretti, A. (author)
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 (creator_code:org_t)
2016-02-16
2015
English.
In: Nanocomposites. - : Taylor and Francis Inc.. - 2055-0332 .- 2055-0324. ; 1:4, s. 195-203
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • Cellulose nanocrystals (CNC) and microcrystals (CMC) were selected as reinforcing fillers for poly(2-ethyl-2-oxazoline), a water-soluble thermoplastic adhesive widely used in the restoration of oil paintings. Thin composite films containing 5, 10, and 30 wt% of CNC or CMC were produced by solution mixing and casting. UV-vis spectroscopy showed how CNC preserved the adhesive transparency even at the highest CNC content, while for CMC, a progressive loss of transparency was observed. Thermal analysis evidenced a progressive increase of the glass transition temperature of the polymer matrix induced by CNC, while no effects were observed for CMC. Both micro- and nanocellulose were able to improve the elastic modulus and reduce the thermal expansion coefficient and creep compliance of the adhesive, with effects more pronounced for CNC nanoparticles. Finally, single-lap shear test on bonded ancient oil painting substrates confirmed the improved dimensional stability of the joint imparted by CNC in the adhesive under both quasi-static and creep conditions. 

Subject headings

TEKNIK OCH TEKNOLOGIER  -- Industriell bioteknik -- Biomaterial (hsv//swe)
ENGINEERING AND TECHNOLOGY  -- Industrial Biotechnology -- Bio Materials (hsv//eng)

Keyword

Adhesion
Cellulose
Cultural heritage
Mechanical properties
Nanocomposites

Publication and Content Type

ref (subject category)
art (subject category)

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Cataldi, A.
Berglund, Lars, ...
Deflorian, F.
Pegoretti, A.
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ENGINEERING AND TECHNOLOGY
ENGINEERING AND ...
and Industrial Biote ...
and Bio Materials
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Nanocomposites
By the university
Royal Institute of Technology

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