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Structure and tunea...
Structure and tuneable luminescence in polymeric zinc compounds based on 3-(3-pyridyl)-5-(4-pyridyl)-1,2,4-triazole
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- Gusev, Alexey (author)
- Russian Acad Sci, NS Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia.
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- Braga, Elena (author)
- Russian Acad Sci, NS Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia.
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- Baluda, Yuriy (author)
- Russian Acad Sci, NS Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia.
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- Kiskin, Mikhail (author)
- Russian Acad Sci, NS Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia.
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- Kryukova, Mariya (author)
- St Petersburg State Univ, Inst Chem, Univ Skaya Nab 7-9, St Petersburg 199034, Russia.
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- Karaush-Karmazin, Nataliya (author)
- Bohdan Khmelnytsky Natl Univ, Dept Chem & Nanomat Sci, UA-18031 Cherkassy, Ukraine.
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- Baryshnikov, Gleb V. (author)
- KTH,Teoretisk kemi och biologi,Bohdan Khmelnytsky Natl Univ, Dept Chem & Nanomat Sci, UA-18031 Cherkassy, Ukraine.
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- Kuklin, Artem, V (author)
- KTH,Teoretisk kemi och biologi,Sch Engn Sci Chem Biotechnol & Hlth, Div Theoret Chem & Biol, S-10691 Stockholm, Sweden.;Siberian Fed Univ, Dept Sci & Innovat, 79 Svobodny Av, Krasnoyarsk 660041, Russia.
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- Minaev, Boris (author)
- Bohdan Khmelnytsky Natl Univ, Dept Chem & Nanomat Sci, UA-18031 Cherkassy, Ukraine.
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- Ågren, Hans (author)
- KTH,Albanova VinnExcellence Center for Protein Technology, ProNova,Teoretisk kemi och biologi,Henan Univ, Coll Chem & Chem Engn, Kaifeng 475004, Henan, Peoples R China.
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- Linert, Wolfgang (author)
- Vienna Univ Technol, Inst Appl Synthet Chem, Getreidemarkt 9-163, A-1060 Vienna, Austria.
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Russian Acad Sci, NS Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia St Petersburg State Univ, Inst Chem, Univ Skaya Nab 7-9, St Petersburg 199034, Russia. (creator_code:org_t)
- Elsevier BV, 2020
- 2020
- English.
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In: Polyhedron. - : Elsevier BV. - 0277-5387 .- 1873-3719. ; 191
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Abstract
Subject headings
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- Inorganic-organic hybrid polymers based on 3-(3-pyridyl)-5-(4-pyridyl)-1,2,4-triazole (3,4-Hbpt) ligand were synthesized and subsequently characterized by single-crystal X-ray diffraction, FT-IR spectra, elemental analyses, thermogravimetric (TG) analyses and PXRD. The X-ray diffraction analyses revealed that the complexes [Zn(3,4-Hbpt)Cl-2] and [Zn(3,4-Hbpt)Br-2] possess a 1-D helical chain structure constructed of the 3,4-Hbpt ligands connecting the zinc cations. The [Zn(3,4-bpt)(OAc)] complex demonstrates a 2D sheet structure bridged by tridentate 3,4-bpt-anions. All compounds exhibit substantial thermal stability and show photo-fluorescent properties that result from the ligand pi-pi* transition. Ultraviolet-to-visible tunable emission for two of the complexes is observed.
Subject headings
- NATURVETENSKAP -- Kemi -- Oorganisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)
Keyword
- 3-(3-Pyridyl)-5-(4-pyridyl)-1
- 2
- 4-triazole
- Zinc
- X-ray diffraction
- Luminescence
Publication and Content Type
- ref (subject category)
- art (subject category)
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Polyhedron
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- By the author/editor
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Gusev, Alexey
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Braga, Elena
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Baluda, Yuriy
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Kiskin, Mikhail
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Kryukova, Mariya
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Karaush-Karmazin ...
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show more...
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Baryshnikov, Gle ...
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Kuklin, Artem, V
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Minaev, Boris
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Ågren, Hans
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Linert, Wolfgang
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show less...
- About the subject
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Chemical Science ...
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and Inorganic Chemis ...
- Articles in the publication
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Polyhedron
- By the university
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Royal Institute of Technology