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Silver-Catalyzed [3...
Silver-Catalyzed [3+1+1] Annulation of Nitrones with Isocyanoacetates as an Approach to 1,4,5-Trisubstituted Imidazoles
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Lv, L. (author)
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Chen, Y. (author)
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- Shatskiy, Andrey (author)
- KTH,Organisk kemi
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- Liu, Jian quan (author)
- KTH,Kemi,School of Chemistry and Materials Science, Jiangsu Key Laboratory of Green Synthesis for Functional Materials, Jiangsu Normal University, Xuzhou, Jiangsu 221116, China
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Liu, X. (author)
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- Kärkäs, Markus D. (author)
- KTH,Organisk kemi
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Wang, X. -S (author)
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(creator_code:org_t)
- 2020-12-23
- 2021
- English.
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In: European Journal of Organic Chemistry. - : Wiley. - 1434-193X .- 1099-0690. ; 2021:6, s. 964-968
- Related links:
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https://doi.org/10.1...
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https://doi.org/10.1...
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https://urn.kb.se/re...
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Abstract
Subject headings
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- A silver-catalyzed protocol for [3+1+1] annulation of nitrones and isocyanoacetates is reported. The reaction is proposed to proceed through sequential [3+2] cycloaddition, ring-opening, cyclization-oxidation, and dealkylation, allowing access to a broad scope of valuable polysubstituted imidazoles in high yields.
Subject headings
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
Keyword
- Annulations
- Cascade reactions
- Imidazoles
- Isocyanides
- Silver
Publication and Content Type
- ref (subject category)
- art (subject category)
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