Revealing Morphology Evolution in Highly Efficient Bulk Heterojunction and Pseudo-Planar Heterojunction Solar Cells by Additives Treatment

• Additives treatment is as a very effective strategy to optimize bulk heterojunction (BHJ) morphology. However, the inherent working mechanism of this strategy still lacks systematical investigations in non-fullerene-acceptors-based organic solar cells (OSCs). Herein, a series of BHJ and pseudo-planar heterojunction (PPHJ) OSCs using PM6 and IT-4F as the electron donor/acceptor pair, are developed to unveil the promoting effect of solvent additive 1, 8-diiodooctane (DIO) on active layer morphologies and device performance. The study clearly demonstrates that DIO can increase the crystallinity of IT-4F significantly, while it has less impact on PM6. It is notable that a new efficiency-determining crystalline balanced factor (CCLpolymer/CCLacceptor) is put forward, indicating that the more balanced CCLpolymer/CCLacceptor results in more balanced charge mobility and much better short-circuit current densities (Jsc) and fill factors (FF) of OSCs. The PPHJ blend film of PM6/IT-4F(DIO) exhibits enhanced crystallinity with more balanced CCL and favorable hierarchical distribution morphology, contributing to a champion efficiency of 13.70% with a record Jsc of 20.98 mA cm−2 and a remarkable FF of 75.9%. This work not only reveals the underlying mechanism of DIO caused morphology evolution, but also achieves highly efficient PPHJ OSCs with superior thermal stability by elaborately controlling the morphology of PPHJ film.

Subject headings

NATURVETENSKAP  -- Kemi -- Materialkemi (hsv//swe)

NATURAL SCIENCES  -- Chemical Sciences -- Materials Chemistry (hsv//eng)

NATURVETENSKAP  -- Kemi -- Annan kemi (hsv//swe)

NATURAL SCIENCES  -- Chemical Sciences -- Other Chemistry Topics (hsv//eng)

Keyword

bulk heterojunctions

crystal coherence length

morphology regulation

organic solar cells

pseudo-planar heterojunctions

Additives

Crystallinity

Efficiency

Heterojunctions

Bulk heterojunction

Bulk heterojunction (BHJ)

Charge mobilities

Device performance

Heterojunction solar cells

Hierarchical distribution

Morphology evolution

Working mechanisms

Morphology

Publication and Content Type

ref (subject category)

art (subject category)