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Studies on the synt...
Studies on the synthesis of β-thevinone derivatives
- Article/chapterEnglish1998
Publisher, publication year, extent ...
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Elsevier BV,1998
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printrdacarrier
Numbers
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LIBRIS-ID:oai:DiVA.org:kth-317900
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https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-317900URI
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https://doi.org/10.1016/S0040-4020(98)00551-1DOI
Supplementary language notes
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Language:English
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Summary in:English
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Classification
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Subject category:ref swepub-contenttype
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Subject category:art swepub-publicationtype
Notes
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QC 20220915
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The reactions of β-thevinone and β-dihydrothevinone with tert- butylmagnesium chloride and n-propylmagnesium bromide were investigated. Further chemical transformations (N-demethylation, N-alkylation, O- demethylation) of the tertiary alcohols afforded the known β-buprenorphine and the hitherto unknown β-etorphine and β-dihydroetorphine. The by- products of these reactions were also isolated, their structures identified, and the mode of their formation was explained.
Subject headings and genre
Added entries (persons, corporate bodies, meetings, titles ...)
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Szabó, Zoltan,Associate professorKTH,Kemi(Swepub:kth)u1ffpq7p
(author)
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Garadnay, S.
(author)
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Miklós, S.
(author)
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Makleit, S.
(author)
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KTHKemi
(creator_code:org_t)
Related titles
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In:Tetrahedron: Elsevier BV54:31, s. 9143-91520040-40201464-5416
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