Search: onr:"swepub:oai:DiVA.org:kth-321048" >
Narrowing the toler...
Narrowing the tolerance factor limits for hybrid organic-inorganic dicyanamide-perovskites
-
- Garcia-Ben, Javier (author)
- Univ A Coruna, Ctr Investigac Cient Avanzadas CICA, Quimolmat, Rua Carballeiras, La Coruna 15071, Spain.;Univ A Coruna, Dept Quim, Fac Ciencias, Campus Zapateira, La Coruna 15008, Spain.
-
- Garcia Fernandez, Alberto (author)
- KTH,Tillämpad fysikalisk kemi
-
- Dafonte-Rodriguez, Pedro (author)
- Univ A Coruna, Ctr Investigac Cient Avanzadas CICA, Quimolmat, Rua Carballeiras, La Coruna 15071, Spain.;Univ A Coruna, Dept Quim, Fac Ciencias, Campus Zapateira, La Coruna 15008, Spain.
-
show more...
-
- Delgado-Ferreiro, Ignacio (author)
- Univ A Coruna, Ctr Investigac Cient Avanzadas CICA, Quimolmat, Rua Carballeiras, La Coruna 15071, Spain.;Univ A Coruna, Dept Quim, Fac Ciencias, Campus Zapateira, La Coruna 15008, Spain.
-
- Cappel, Ute B. (author)
- KTH,Tillämpad fysikalisk kemi
-
- Castro-Garcia, Socorro (author)
- Univ A Coruna, Ctr Investigac Cient Avanzadas CICA, Quimolmat, Rua Carballeiras, La Coruna 15071, Spain.;Univ A Coruna, Dept Quim, Fac Ciencias, Campus Zapateira, La Coruna 15008, Spain.
-
- Sanchez-Andujar, Manuel (author)
- Univ A Coruna, Ctr Investigac Cient Avanzadas CICA, Quimolmat, Rua Carballeiras, La Coruna 15071, Spain.;Univ A Coruna, Dept Quim, Fac Ciencias, Campus Zapateira, La Coruna 15008, Spain.
-
- Manuel Bermudez-Garcia, Juan (author)
- Univ A Coruna, Ctr Investigac Cient Avanzadas CICA, Quimolmat, Rua Carballeiras, La Coruna 15071, Spain.;Univ A Coruna, Dept Quim, Fac Ciencias, Campus Zapateira, La Coruna 15008, Spain.
-
- Antonia Senaris-Rodriguez, Maria (author)
- Univ A Coruna, Ctr Investigac Cient Avanzadas CICA, Quimolmat, Rua Carballeiras, La Coruna 15071, Spain.;Univ A Coruna, Dept Quim, Fac Ciencias, Campus Zapateira, La Coruna 15008, Spain.
-
show less...
-
Univ A Coruna, Ctr Investigac Cient Avanzadas CICA, Quimolmat, Rua Carballeiras, La Coruna 15071, Spain;Univ A Coruna, Dept Quim, Fac Ciencias, Campus Zapateira, La Coruna 15008, Spain. Tillämpad fysikalisk kemi (creator_code:org_t)
- Elsevier BV, 2022
- 2022
- English.
-
In: Journal of Solid State Chemistry. - : Elsevier BV. - 0022-4596 .- 1095-726X. ; 316, s. 123635-
- Related links:
-
https://doi.org/10.1...
-
show more...
-
https://urn.kb.se/re...
-
https://doi.org/10.1...
-
show less...
Abstract
Subject headings
Close
- In this work we focus in setting the limits of the tolerance factor and the size of the A-cations that stabilize the perovskite structure in hybrid dicyanamide compounds [A][Mn(dca)3]. For this purpose, we propose an alter-native, simple approach to calculate a more realistic effective ionic radius for the large and anisotropic A-cations often present in these type of compounds. We test the proposed procedure by analysing the crystal structures of [A][Mn(dca)3] dicyanamide hybrids reported in the literature and recalculating the tolerance factors of such compounds, as well as by preparing five new [A][Mn(dca)3] members, discussing also the influence of the A -cation shape in the stability limits of the perovskite structure. Interestingly, such methodology is not only useful to develop new compounds of the emerging family of (multi)functional multi(stimuli)-responsive dicyanamide materials but can also be applied to other hybrid organic-inorganic perovskites and related materials.
Subject headings
- NATURVETENSKAP -- Kemi -- Materialkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Materials Chemistry (hsv//eng)
Keyword
- Hybrid organic-inorganic perovskites
- Tolerance factor
- Dicyanamide compounds
- A-cation volume
- Promolecule isosurface
Publication and Content Type
- ref (subject category)
- art (subject category)
Find in a library
To the university's database