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  • Proietti, GiampieroKTH,Organisk kemi (author)

Ultralight aerogels via supramolecular polymerization of a new chiral perfluoropyridine-based sulfonimidamide organogelator

  • Article/chapterEnglish2024

Publisher, publication year, extent ...

  • Royal Society of Chemistry (RSC),2024
  • printrdacarrier

Numbers

  • LIBRIS-ID:oai:DiVA.org:kth-347069
  • https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-347069URI
  • https://doi.org/10.1039/d3nr06460cDOI

Supplementary language notes

  • Language:English
  • Summary in:English

Part of subdatabase

Classification

  • Subject category:ref swepub-contenttype
  • Subject category:art swepub-publicationtype

Notes

  • QC 20240603
  • Chiral and enantiopure perfluorinated sulfonimidamides act as low-molecular weight gelators at low critical gelation concentration (<1 mg mL-1) via supramolecular polymerization in nonpolar organic solvents and more heterogenic mixtures, such as biodiesel and oil. Freeze-drying of the organogel leads to ultralight aerogel with extremely low density (1 mg mL-1). The gelation is driven by hydrogen bonding resulting in a helical molecular ordering and unique fibre assemblies as confirmed by scanning electron microscopy, CD spectroscopy, and computational modeling of the supramolecular structure.

Subject headings and genre

Added entries (persons, corporate bodies, meetings, titles ...)

  • Axelsson, AntonKTH,Organisk kemi(Swepub:kth)u19gqt9d (author)
  • Capezza, Antonio JoseKTH,Polymera material(Swepub:kth)u1fmvhux (author)
  • Todarwal, YogeshKTH,Teoretisk kemi och biologi(Swepub:kth)u124wczn (author)
  • Kuzmin, JuliusKTH,Organisk kemi(Swepub:kth)u1ka0hch (author)
  • Linares, Mathieu,1979-KTH,Teoretisk kemi och biologi(Swepub:kth)u1o6qsz8 (author)
  • Norman, PatrickKTH,Teoretisk kemi och biologi(Swepub:kth)u1c4e2k0 (author)
  • Szabo, Zoltan,Associate professorKTH,Organisk kemi(Swepub:kth)u1ffpq7p (author)
  • Lendel, ChristoferKTH,Tillämpad fysikalisk kemi(Swepub:kth)u1zepbos (author)
  • Olsson, RichardKTH,Polymera material(Swepub:kth)u1ob386f (author)
  • Dinér, PeterKTH,Organisk kemi(Swepub:kth)u11v8usm (author)
  • KTHOrganisk kemi (creator_code:org_t)

Related titles

  • In:Nanoscale: Royal Society of Chemistry (RSC)16:15, s. 7603-76112040-33642040-3372

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