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- Shi, Yu (author)
A Suzuki-type cross-coupling reaction of arylacetylene halides with arylboronic acids
- Article/chapterEnglish2011
Publisher, publication year, extent ...
- 2011-04-26
- Wiley,2011
- printrdacarrier
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- LIBRIS-ID:oai:DiVA.org:kth-37164
- https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-37164URI
- https://doi.org/10.1002/aoc.1795DOI
Supplementary language notes
- Language:English
- Summary in:English
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- SwePubSwePub
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Notes
- A PdCl(2)-catalyzed direct alkynylation of arylboronic acids to give diarylacetylenes is described. The optimal conditions using PdCl(2) as catalyst, MeOH-PhMe-H(2)O as solvent and K(2)CO(3) as base effectively suppressed the formation of homo-coupling product and afforded moderate to good yield of the desired unsymmetrical coupling product. This reaction represents a Suzuki-type sp(2)(C-B)-sp(C-X) cross-coupling.
Subject headings and genre
- NATURVETENSKAP Kemi hsv//swe
- NATURAL SCIENCES Chemical Sciences hsv//eng
- Suzuki cross-coupling
- diarylacetylene
- palladium chloride
- alkynylation
- Chemistry
- Kemi
Added entries (persons, corporate bodies, meetings, titles ...)
- Li, Xiaoyu (author)
- Liu, Jianhui (author)
- Jiang, Wenfeng (author)
- Sun, LichengKTH,Organisk kemi(Swepub:kth)u1umfd9h (author)
- KTHOrganisk kemi (creator_code:org_t)
Related titles
- In:Applied organometallic chemistry: Wiley25:7, s. 514-5200268-26051099-0739
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