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C-H activation in s...
C-H activation in strongly acidic media. The co-catalytic effect of the reaction medium
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- Ahlquist, Mårten (author)
- California Institute of Technology
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Periana, Roy A. (author)
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Goddard, William A., III (author)
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(creator_code:org_t)
- Royal Society of Chemistry (RSC), 2009
- 2009
- English.
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In: Chemical Communications. - : Royal Society of Chemistry (RSC). - 1359-7345 .- 1364-548X. ; :17, s. 2373-2375
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Abstract
Subject headings
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- Quantum mechanical (QM) results are used to establish the role of sulfuric acid solvent in facilitating the reaction between Pt(II)(bpym)Cl(2) (bpym = 2,2'-bipyrimidinyl) and methane; coordination of methane to the platinum catalyst is found to be catalyzed by the acidic medium.
Subject headings
- NATURVETENSKAP -- Kemi -- Teoretisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Theoretical Chemistry (hsv//eng)
Keyword
- methane
- platinum
- platinum complex
- pyrimidine derivative
- sulfuric acid
Publication and Content Type
- ref (subject category)
- art (subject category)
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