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Structure and Bondi...
Structure and Bonding of the Manganese(II) Phosphide Complex (t-BuPH(2))(eta(5)-Cp)Mn{mu-(t-BuPH)}(2)Mn(Cp)(t-BuPH(2))
- Article/chapterEnglish2012
Publisher, publication year, extent ...
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2011-12-19
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American Chemical Society (ACS),2012
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printrdacarrier
Numbers
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LIBRIS-ID:oai:DiVA.org:kth-75574
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https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-75574URI
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https://doi.org/10.1021/om200381pDOI
Supplementary language notes
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Language:English
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Summary in:English
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Classification
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Subject category:ref swepub-contenttype
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Subject category:art swepub-publicationtype
Notes
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QC 20120206
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Rather than achieving bis-deprotonation of the phosphine, reaction of Cp2Mn (Cp = cyclopentadienyl) with t-BuPH2 at room temperature yields monodeprotonation of half of the available phosphine in the product (t-BuPH2)(η5-Cp)Mn{μ-(t-BuPH)}2Mn(Cp)(t-BuPH2) (1). This complex comprises a Mn(II) phosphide and is a dimer in the solid state, containing a Mn2P2 diamond core. Consistent with the observation of a relatively short intermetal distance of 2.8717(4) Å in 1, DFT analysis of the full structure points to a singlet ground state stabilized by a direct Mn–Mn single bond. This is in line with the diamagnetic character of 1 and an 18-electron count at Mn.
Subject headings and genre
Added entries (persons, corporate bodies, meetings, titles ...)
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Less, R.J.
(author)
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Haywood, J.
(author)
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Melen, Rebecca L.
(author)
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Thompson, R.L.
(author)
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Wheatley, A.E.
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Wright, D.S.
(author)
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Johansson, Adam JohannesKTH,Fysikalisk kemi(Swepub:kth)u1cyjnbh
(author)
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Kloo, LarsKTH,Organisk kemi(Swepub:kth)u1jrdr1m
(author)
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KTHFysikalisk kemi
(creator_code:org_t)
Related titles
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In:Organometallics: American Chemical Society (ACS)31:1, s. 23-260276-73331520-6041
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