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Enantioselective Or...
Enantioselective Organocatalytic Hydrophosphination of α,β-Unsaturated Aldehydes
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- Ibrahem, Ismail (author)
- Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University
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- Rios, Ramon (author)
- Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University
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- Vesely, Jan (author)
- Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University
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- Hammar, Peter (author)
- KTH,Teoretisk kemi
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- Eriksson, Lars (author)
- Department of Structural Chemistry, Arrhenius Laboratory, Stockholm University
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- Himo, Fahmi (author)
- KTH,Teoretisk kemi
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- Córdova, Armando (author)
- Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University
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(creator_code:org_t)
- Wiley, 2007
- 2007
- English.
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In: Angewandte Chemie International Edition. - : Wiley. - 1433-7851 .- 1521-3773. ; 46:24, s. 4507-4510
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- Keeping it simple: Optically active phosphine derivatives can be obtained in high yields and in up to 99% ee by using simple chiral amines to catalyze the hydrophosphination of α,β-unsaturated aldehydes (see scheme, green sphere = chiral group). The synthetic utility of this highly chemo- and enantioselective transformation was exemplified by the one-pot asymmetric synthesis of β-phosphine oxide acids.
Subject headings
- MEDICIN OCH HÄLSOVETENSKAP -- Medicinska och farmaceutiska grundvetenskaper -- Andra medicinska och farmaceutiska grundvetenskaper (hsv//swe)
- MEDICAL AND HEALTH SCIENCES -- Basic Medicine -- Other Basic Medicine (hsv//eng)
Keyword
- Aldehydes
- Asymmetric synthesis
- Conjugate addition
- Organocatalysis
- Phosphanes
- Chemistry
- Kemi
Publication and Content Type
- ref (subject category)
- art (subject category)
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