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Enhancement of the wet properties of transparent chitosan-acetic-acid-salt films using microfibrillated cellulose

Nordqvist, David (author)
KTH,Fiber- och polymerteknologi
Idermark, Johan (author)
KTH,Fiber- och polymerteknologi
Hedenqvist, Mikael S. (author)
KTH,Fiber- och polymerteknologi
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Gällstedt, M. (author)
STFI-Packforsk
Ankerfors, M. (author)
STFI-Packforsk
Lindström, T. (author)
STFI-Packforsk
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 (creator_code:org_t)
2007-07-24
2007
English.
In: Biomacromolecules. - : American Chemical Society (ACS). - 1525-7797 .- 1526-4602. ; 8:8, s. 2398-2403
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • This report presents a new route to enhance the wet properties of chitosan-acetic-acid-salt films using microfibrillated cellulose (MFC). The enhancement makes it easier to form chitosan-acetic-acid-salt films into various shapes at room temperature in the wet state. Chitosan with MFC was compared with the well-known buffer treatment. It was observed that films containing 5 wt % MFC were visually identical to the buffered/unbuffered films without MFC. Field-emission scanning electron microscopy indicated that MFC formed a network with uniformly distributed fibrils and fibril bundles in the chitosan matrix. The addition of MFC reduced the risk of creases and deformation in the wet state because of a greater wet stiffness. The wet films containing MFC were also extensible. Although the stiffness, strength and extensibility were highest for the buffered films, the wet strength of the MFC-containing unbuffered films was sufficient for wet forming operations. The effects of MFC on the mechanical properties of the dry chitosan films were small or absent. It was concluded that the addition of MFC is an acceptable alternative to buffering for shaping chitosan films/products in the wet state. The advantages are that the "extra" processing step associated with buffering is unnecessary and that the film matrix remains more water-soluble.

Subject headings

NATURVETENSKAP  -- Kemi -- Polymerkemi (hsv//swe)
NATURAL SCIENCES  -- Chemical Sciences -- Polymer Chemistry (hsv//eng)

Keyword

Acetic acid
Mechanical properties
Scanning electron microscopy
Solubility
Stiffness
Wetting Buffer treatment
Chitosan-acetic-acid-salt films
Film matrix
Microfibrillated cellulose
Polymer chemistry
Polymerkemi

Publication and Content Type

ref (subject category)
art (subject category)

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