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Morphology changes ...
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Eriksson, Mats,1963-Linköpings universitet,Kemiska och optiska sensorsystem,Tekniska fakulteten,Tillämpad Fysik
(author)
Morphology changes of thin Pd films grown on SiO2: influence of adsorbates and temperature
- Article/chapterEnglish1999
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Numbers
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LIBRIS-ID:oai:DiVA.org:liu-118324
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https://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-118324URI
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https://doi.org/10.1016/S0040-6090(98)01395-9DOI
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Language:English
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Summary in:English
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Subject category:ref swepub-contenttype
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Subject category:art swepub-publicationtype
Notes
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Under certain conditions morphology changes occur when thin Pd films, grown on SiO2 at room temperature, are subject to elevated temperatures. First holes in the metal are observed, followed by network formation and finally isolation of metal islands. This process is known as agglomeration. The influence of gas exposures on this restructuring process has been studied by following variations in the capacitance of the structure and by atomic force microscopy, transmission electron microscopy and ultraviolet photoelectron spectroscopy. The capacitance measurements show that carbonaceous species have an impeding influence on the rate of agglomeration and may lock the film structure in a thermodynamic non-equilibrium state. By removing these species with oxygen exposure, i.e. by forming volatile CO and CO2, a clean surface is obtained and the agglomeration process can proceed. High oxygen or hydrogen coverages also lower the rate of restructuring, compared to the case of a clean surface. For the clean Pd surface, an apparent activation energy of 0.64 eV is found for the restructuring process.
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Olsson, LarsLinköpings universitet,Institutionen för medicin och hälsa(Swepub:liu)larol71
(author)
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Erlandsson, RagnarLinköpings universitet,Kemiska och optiska sensorsystem,Tekniska fakulteten(Swepub:liu)rager23
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Helmersson, UlfLinköpings universitet,Plasma och ytbeläggningsfysik,Tekniska fakulteten(Swepub:liu)ulfhe30
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Ekedahl, Lars-GunnarLinköpings universitet,Institutionen för fysik, kemi och biologi(Swepub:liu)larek85
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Linköpings universitetKemiska och optiska sensorsystem
(creator_code:org_t)
Related titles
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In:Thin Solid Films342:1-2, s. 297-3060040-60901879-2731
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