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- Lazzaroni, R.Service de Chimie des Matériaux Nouveaux, Département des Matériaux et Procédés, Université de Mons-Hainaut, Mons, Belgium (author)
The chemical and electronic structure of the interface between aluminum and conjugated polymers
- Article/chapterEnglish1994
Publisher, publication year, extent ...
- Elsevier,1994
- printrdacarrier
Numbers
- LIBRIS-ID:oai:DiVA.org:liu-124170
- https://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-124170URI
- https://doi.org/10.1016/0013-4686(94)80059-6DOI
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- Language:English
- Summary in:English
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Notes
- The chemical and electronic structure of the interface between aluminum and several proto-typical conjugated systems is investigated with a combined experimental and theoretical approach. The experiments consists of following the evolution of the polymer surface during the early stages of aluminum deposition, with X-ray and Ultraviolet Photoelectron Spectroscopies (XPS, UPS). In parallel, quantum chemical calculations are performed on model oligomer systems interacting with isolated Al atoms. Aluminum is found to interact strongly with the polymer chain. New covalent Al-carbon bonds are formed along the polymer backbone; the chain geometry is deeply modified and the π electron conjugation can be dramatically reduced.
Subject headings and genre
- NATURVETENSKAP Fysik hsv//swe
- NATURAL SCIENCES Physical Sciences hsv//eng
- NATURVETENSKAP Kemi hsv//swe
- NATURAL SCIENCES Chemical Sciences hsv//eng
- polymer-based devices
- interface chemistry
- electronic structure
Added entries (persons, corporate bodies, meetings, titles ...)
- Brédas, J. L.Service de Chimie des Matériaux Nouveaux, Département des Matériaux et Procédés, Université de Mons-Hainaut, Mons, Belgium (author)
- Dannetun, PerService de Chimie des Matériaux Nouveaux, Département des Matériaux et Procédés, Université de Mons-Hainaut, Mons, Belgium(Swepub:liu)perda20 (author)
- Fredriksson, C.Service de Chimie des Matériaux Nouveaux, Département des Matériaux et Procédés, Université de Mons-Hainaut, Mons, Belgium (author)
- Stafström, SvenService de Chimie des Matériaux Nouveaux, Département des Matériaux et Procédés, Université de Mons-Hainaut, Mons, Belgium(Swepub:liu)svest87 (author)
- Salaneck, William R.Linköpings universitet,Institutionen för fysik, kemi och biologi,Tekniska högskolan(Swepub:liu)wilsa67 (author)
- Service de Chimie des Matériaux Nouveaux, Département des Matériaux et Procédés, Université de Mons-Hainaut, Mons, BelgiumInstitutionen för fysik, kemi och biologi (creator_code:org_t)
Related titles
- In:Electrochimica Acta: Elsevier39:2, s. 235-2440013-46861873-3859
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