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Naphthalenediimide Polymers with Finely Tuned In-Chain pi-Conjugation: Electronic Structure, Film Microstructure, and Charge Transport Properties
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- Erdmann, Tim (author)
- Leibniz Institute Polymerforschung Dresden eV, Germany; Technical University of Dresden, Germany; Polyera Corp, IL 60077 USA
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- Fabiano, Simone (author)
- Linköpings universitet,Fysik och elektroteknik,Tekniska fakulteten,Polyera Corp, IL 60077 USA
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- Milian-Medina, Begona (author)
- University of Valencia, Spain; Ciudad University of Cantoblanco, Spain
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- (creator_code:org_t)
- 2016-08-30
- 2016
- English.
- In: ADVANCED MATERIALS. - : WILEY-V C H VERLAG GMBH. - 0935-9648 .- 1521-4095. ; 28:41, s. 9169-
- Journal article (peer-reviewed)
Abstract
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- Naphthalenediimide-based random copolymers (PNDI-TVTx) with different p-conjugated dithienylvinylene (TVT) versus p-nonconjugated dithienylethane (TET) unit ratios (x = 100 -amp;gt; 0%) are investigated. The PNDI-TVTx-transistor electron/hole mobilities are affected differently, a result rationalized by molecular orbital topologies and energies, with hole mobility vanishing but electron mobility decreasing only by approximate to 2.5 times when going from x = 100% to 40%.
Subject headings
- NATURVETENSKAP -- Fysik -- Den kondenserade materiens fysik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Condensed Matter Physics (hsv//eng)
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- Hanifi, David
- Chen, Zhihua
- Berggren, Magnus
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- Salleo, Alberto
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