Search: onr:"swepub:oai:DiVA.org:liu-139735" >
Ti2Au2C and Ti3Au2C...
Ti2Au2C and Ti3Au2C2 formed by solid state reaction of gold with Ti2AlC and Ti3AlC2
-
- Fashandi, Hossein (author)
- Linköpings universitet,Tunnfilmsfysik,Tekniska fakulteten
-
- Lai, Chung-Chuan (author)
- Linköpings universitet,Tunnfilmsfysik,Tekniska fakulteten
-
- Dahlqvist, Martin (author)
- Linköpings universitet,Tunnfilmsfysik,Tekniska fakulteten
-
show more...
-
- Lu, Jun (author)
- Linköpings universitet,Tunnfilmsfysik,Tekniska fakulteten
-
- Rosén, Johanna (author)
- Linköpings universitet,Tunnfilmsfysik,Tekniska fakulteten
-
- Hultman, Lars (author)
- Linköpings universitet,Tunnfilmsfysik,Tekniska fakulteten
-
- Greczynski, Grzegorz (author)
- Linköpings universitet,Tunnfilmsfysik,Tekniska fakulteten
-
- Andersson, Mike (author)
- Linköpings universitet,Tillämpad sensorvetenskap,Tekniska fakulteten
-
- Lloyd Spetz, Anita (author)
- Linköpings universitet,Tillämpad sensorvetenskap,Tekniska fakulteten
-
- Eklund, Per (author)
- Linköpings universitet,Tunnfilmsfysik,Tekniska fakulteten
-
show less...
-
(creator_code:org_t)
- Royal Society of Chemistry, 2017
- 2017
- English.
-
In: Chemical Communications. - : Royal Society of Chemistry. - 1359-7345 .- 1364-548X. ; 53:69, s. 9554-9557
- Related links:
-
https://liu.diva-por... (primary) (Raw object)
-
show more...
-
https://liu.diva-por... (primary) (Raw object)
-
https://urn.kb.se/re...
-
https://doi.org/10.1...
-
show less...
Abstract
Subject headings
Close
- Incorporation of layers of noble metals in non-van der Waals layered materials may be used to form novel layered compounds. Recently, we demonstrated a high-temperature-induced exchange process of Au with Si in the layered phase Ti3SiC2, resulting in the formation of Ti3AuC2 and Ti3Au2C2. Here, we generalize this technique showing that Au/Ti2AlC and Au/Ti3AlC2 undergo an exchange reaction at 650 [degree]C to form Ti2Au2C and Ti3Au2C2 and determine their structures by electron microscopy, X-ray diffraction, and ab initio calculations. These results imply that noble-metal-containing layered phases should be possible to synthesize in many systems. The metal to be introduced should be inert to the transition-metal carbide layers, and exhibit negative heat of mixing with the initial A element in a liquid phase or two-phase liquid/solid region at the annealing temperature.
Subject headings
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Publication and Content Type
- ref (subject category)
- art (subject category)
Find in a library
To the university's database
- By the author/editor
-
Fashandi, Hossei ...
-
Lai, Chung-Chuan
-
Dahlqvist, Marti ...
-
Lu, Jun
-
Rosén, Johanna
-
Hultman, Lars
-
show more...
-
Greczynski, Grze ...
-
Andersson, Mike
-
Lloyd Spetz, Ani ...
-
Eklund, Per
-
show less...
- About the subject
-
- NATURAL SCIENCES
-
NATURAL SCIENCES
-
and Chemical Science ...
- Articles in the publication
-
Chemical Communi ...
- By the university
-
Linköping University