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Magnetic properties...
Magnetic properties of Cr2AlB2, Cr3AlB4, and CrB powders
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- Kota, Sankalp (author)
- Drexel Univ, PA 19104 USA
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- Wang, Wenzhen (author)
- Drexel Univ, PA 19104 USA
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- Lu, Jun (author)
- Linköpings universitet,Tunnfilmsfysik,Tekniska fakulteten
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- Natu, Varun (author)
- Drexel Univ, PA 19104 USA
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- Opagiste, Christine (author)
- Univ Grenoble Alpes, France
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- Ying, Guobing (author)
- Drexel Univ, PA 19104 USA
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- Hultman, Lars (author)
- Linköpings universitet,Tunnfilmsfysik,Tekniska fakulteten
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- May, Steven J. (author)
- Drexel Univ, PA 19104 USA
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- Barsoum, Michel W. (author)
- Drexel Univ, PA 19104 USA
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(creator_code:org_t)
- ELSEVIER SCIENCE SA, 2018
- 2018
- English.
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In: Journal of Alloys and Compounds. - : ELSEVIER SCIENCE SA. - 0925-8388 .- 1873-4669. ; 767, s. 474-482
- Related links:
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https://www.scienced...
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- The MAB phases are ternary, atomically laminated compounds that crystallize with orthorhombic structures and consist of transition metal (M) boride sublattices interleaved with single or double layers of Al. To date, the magnetic properties of ferromagnetic Fe(2)AIB(2) have been well-studied experimentally, but those of most end member MAB phases with other transition metals remain poorly understood. Herein, predominantly single-phase Cr(3)AIB(4) and Cr(2)AIB(2) powders, with minor amounts of CrB impurities, were synthesized by heating mixtures of chromium monoboride (CrB), aluminum (Al), and boron or CrB and Al under flowing Ar. These reactants were found to substantially suppress the formation of undesired phases in the Cr-Al-B system. The magnetic properties of Cr(3)AIB(4), Cr(2)AIB(2) and CrB powders were characterized. All compounds exhibit paramagnetic behavior down to 4 K, with susceptibilities that are quite weakly temperature dependent at higher temperatures and a Curie-Weiss-like component prominent at low temperatures. Magnetization isotherms of the three compounds, showed approximately linear behavior above 5 kOe and no saturation of the magnetic moment up to 40 kOe, which is consistent with paramagnetism. The magnitude of the magnetic moments showed little variation with composition, on a per Cr atom basis. While the exact nature of the Curie-Weiss component is not entirely clear, we tentatively attribute it to dilute extrinsic impurities. (C) 2018 Elsevier B.V. All rights reserved.
Subject headings
- NATURVETENSKAP -- Kemi -- Oorganisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)
Keyword
- MAB phases; Borides; Nanolayered structure; Magnetic properties; Paramagnetism
Publication and Content Type
- ref (subject category)
- art (subject category)
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