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High-Pressure Polym...
High-Pressure Polymeric Nitrogen Allotrope with the Black Phosphorus Structure
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- Laniel, Dominique (author)
- Univ Bayreuth, Germany
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- Winlder, Bioern (author)
- Goethe Univ Frankfurt, Germany
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- Fedotenko, Timofey (author)
- Univ Bayreuth, Germany
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- Pakhomova, Anna (author)
- DESY, Germany
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- Chariton, Stella (author)
- Univ Chicago, IL 60637 USA
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- Milman, Victor (author)
- Dassault Syst BIOVIA, England
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- Prakapenka, Vitali (author)
- Univ Chicago, IL 60637 USA
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- Dubrovinsky, Leonid (author)
- Univ Bayreuth, Germany
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- Doubrovinckaia, Natalia (author)
- Linköpings universitet,Teoretisk Fysik,Tekniska fakulteten,Univ Bayreuth, Germany
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(creator_code:org_t)
- AMER PHYSICAL SOC, 2020
- 2020
- English.
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In: Physical Review Letters. - : AMER PHYSICAL SOC. - 0031-9007 .- 1079-7114. ; 124:21
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- Studies of polynitrogen phases are of great interest for fundamental science and for the design of novel high energy density materials. Laser heating of pure nitrogen at 140 GPa in a diamond anvil cell led to the synthesis of a polymeric nitrogen allotrope with the black phosphorus structure, bp-N. The structure was identified in situ using synchrotron single-crystal x-ray diffraction and further studied by Raman spectroscopy and density functional theory calculations. The discovery of bp-N brings nitrogen in line with heavier pnictogen elements, resolves incongruities regarding polymeric nitrogen phases and provides insights into polynitrogen arrangements at extreme densities.
Subject headings
- NATURVETENSKAP -- Kemi -- Oorganisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)
Publication and Content Type
- ref (subject category)
- art (subject category)
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