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Synthesis of MAX ph...
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Ding, HaomingState Key Laboratory for Mechanical Behavior of Materials, Xi’an Jiaotong University, Xi’an, People’s Republic of China; bEngineering Laboratory of Advanced Energy Materials, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, People’s Republic of China
(author)
Synthesis of MAX phases Nb2CuC and Ti2(Al0.1Cu0.9)N by A-site replacement reaction in molten salts
- Article/chapterEnglish2019
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2019-10-01
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Taylor & Francis,2019
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electronicrdacarrier
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LIBRIS-ID:oai:DiVA.org:liu-169090
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https://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-169090URI
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https://doi.org/10.1080/21663831.2019.1672822DOI
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Language:English
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Summary in:English
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Subject category:ref swepub-contenttype
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Subject category:art swepub-publicationtype
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Funding agencies: National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21671195, 51902319, 91426304]; Chinese Academy of SciencesChinese Academy of Sciences [2019VEB0008, 174433KYSB20190019]; Swedish Government Strategic Research
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New MAX phases Ti2(AlxCu1−x)N and Nb2CuC were synthesized by A-site replacement by reacting Ti2AlN and Nb2AlC, respectively, with CuCl2 or CuI molten salt. X-ray diffraction, scanning electron microscopy, and atomically resolved scanning transmission electron microscopy showed complete A-site replacement in Nb2AlC, which lead to the formation of Nb2CuC. However, the replacement of Al in Ti2AlN phase was only close to complete at Ti2(Al0.1Cu0.9)N. Density-functional theory calculations corroborated the structural stability of Nb2CuC and Ti2CuN phases. Moreover, the calculated cleavage energy in these Cu-containing MAX phases are weaker than in their Al-containing counterparts.The preparation of MAX phases Nb2CuC and Ti2(Al0.1Cu0.9)N were realized by A-site replacement in Ti2AlN and Nb2AlN, respectively.
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Li, YoubingEngineering Laboratory of Advanced Energy Materials, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, People’s Republic of China; University of Chinese Academy of Sciences, Beijing, People’s Republic of China
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Lu, JunLinköpings universitet,Tunnfilmsfysik,Tekniska fakulteten(Swepub:liu)junlu07
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Luo, KanEngineering Laboratory of Advanced Energy Materials, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, People’s Republic of China
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Chen, KeEngineering Laboratory of Advanced Energy Materials, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, People’s Republic of China
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Li, MianEngineering Laboratory of Advanced Energy Materials, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, People’s Republic of China
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Persson, Per O. Å.,1971-Linköpings universitet,Tunnfilmsfysik,Tekniska fakulteten(Swepub:liu)perpe25
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Hultman, Lars,Professor,1960-Linköpings universitet,Tunnfilmsfysik,Tekniska fakulteten(Swepub:liu)larhu75
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Eklund, Per,Docent,1977-Linköpings universitet,Tunnfilmsfysik,Tekniska fakulteten(Swepub:liu)perek02
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Du, ShiyuEngineering Laboratory of Advanced Energy Materials, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, People’s Republic of China
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Huang, ZhengrenEngineering Laboratory of Advanced Energy Materials, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, People’s Republic of China
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Chai, ZhifangEngineering Laboratory of Advanced Energy Materials, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, People’s Republic of China
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Wang, HongjieState Key Laboratory for Mechanical Behavior of Materials, Xi’an Jiaotong University, Xi’an, People’s Republic of China
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Huang, PingaState Key Laboratory for Mechanical Behavior of Materials, Xi’an Jiaotong University, Xi’an, People’s Republic of China
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Huang, QingEngineering Laboratory of Advanced Energy Materials, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, People’s Republic of China
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State Key Laboratory for Mechanical Behavior of Materials, Xi’an Jiaotong University, Xi’an, People’s Republic of China; bEngineering Laboratory of Advanced Energy Materials, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, People’s Republic of ChinaEngineering Laboratory of Advanced Energy Materials, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, People’s Republic of China; University of Chinese Academy of Sciences, Beijing, People’s Republic of China
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In:Materials Research Letters: Taylor & Francis7:12, s. 510-5162166-3831
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