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Direct transformati...
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Li, XuechaoSoochow Univ, Peoples R China
(author)
Direct transformation of n-alkane into all-trans conjugated polyene via cascade dehydrogenation
- Article/chapterEnglish2021
Publisher, publication year, extent ...
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2021-05-24
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Oxford University Press,2021
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electronicrdacarrier
Numbers
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LIBRIS-ID:oai:DiVA.org:liu-181700
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https://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-181700URI
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https://doi.org/10.1093/nsr/nwab093DOI
Supplementary language notes
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Language:English
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Summary in:English
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Subject category:ref swepub-contenttype
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Subject category:art swepub-publicationtype
Notes
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Funding Agencies|Ministry of Science and Technology of the Peoples Republic of ChinaMinistry of Science and Technology, China [2017YFA0205000, 2017YFA0205002]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21790053, 51821002]; Collaborative Innovation Center of Suzhou Nano Science Technology; Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD); 111 ProjectMinistry of Education, China - 111 Project; German Research FoundationGerman Research Foundation (DFG) [392178740, 426888090]
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Selective C(sp(3))-H activation is of fundamental importance in processing alkane feedstocks to produce high-value-added chemical products. By virtue of an on-surface synthesis strategy, we report selective cascade dehydrogenation of n-alkane molecules under surface constraints, which yields monodispersed all-trans conjugated polyenes with unprecedented length controllability. We are also able to demonstrate the generality of this concept for alkyl-substituted molecules with programmable lengths and diverse functionalities, and more importantly its promising potential in molecular wiring.
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Niu, KaifengLinköpings universitet,Tunnfilmsfysik,Tekniska fakulteten,Soochow Univ, Peoples R China(Swepub:liu)kaini78
(author)
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Zhang, JunjieSoochow Univ, Peoples R China
(author)
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Yu, XiaojuanKarlsruhe Inst Technol, Germany
(author)
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Zhang, HaimingSoochow Univ, Peoples R China
(author)
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Wang, YueminKarlsruhe Inst Technol, Germany
(author)
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Guo, QingSouthern Univ Sci & Technol, Peoples R China
(author)
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Wang, PengdongChinese Acad Sci, Peoples R China
(author)
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Li, FangsenChinese Acad Sci, Peoples R China
(author)
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Hao, ZhengmingSoochow Univ, Peoples R China
(author)
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Xu, ChaojieSoochow Univ, Peoples R China
(author)
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Tang, YanningSoochow Univ, Peoples R China
(author)
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Xu, ZhichaoSoochow Univ, Peoples R China
(author)
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Lu, ShuaiSoochow Univ, Peoples R China; Chinese Acad Sci, Peoples R China
(author)
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Liu, PengSouthern Univ Sci & Technol, Peoples R China
(author)
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Xue, GuiguSouthern Univ Sci & Technol, Peoples R China
(author)
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Wei, YenTsinghua Univ, Peoples R China
(author)
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Chi, LifengSoochow Univ, Peoples R China
(author)
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Soochow Univ, Peoples R ChinaTunnfilmsfysik
(creator_code:org_t)
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In:National Science Review: Oxford University Press8:102095-51382053-714X
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- By the author/editor
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Li, Xuechao
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Niu, Kaifeng
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Zhang, Junjie
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Yu, Xiaojuan
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Zhang, Haiming
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Wang, Yuemin
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Guo, Qing
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Wang, Pengdong
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Li, Fangsen
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Hao, Zhengming
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Xu, Chaojie
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Tang, Yanning
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Xu, Zhichao
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Lu, Shuai
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Liu, Peng
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Xue, Guigu
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Wei, Yen
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Chi, Lifeng
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NATURAL SCIENCES
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Linköping University