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  • Li, XuechaoSoochow Univ, Peoples R China (author)

Direct transformation of n-alkane into all-trans conjugated polyene via cascade dehydrogenation

  • Article/chapterEnglish2021

Publisher, publication year, extent ...

  • 2021-05-24
  • Oxford University Press,2021
  • electronicrdacarrier

Numbers

  • LIBRIS-ID:oai:DiVA.org:liu-181700
  • https://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-181700URI
  • https://doi.org/10.1093/nsr/nwab093DOI

Supplementary language notes

  • Language:English
  • Summary in:English

Part of subdatabase

Classification

  • Subject category:ref swepub-contenttype
  • Subject category:art swepub-publicationtype

Notes

  • Funding Agencies|Ministry of Science and Technology of the Peoples Republic of ChinaMinistry of Science and Technology, China [2017YFA0205000, 2017YFA0205002]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21790053, 51821002]; Collaborative Innovation Center of Suzhou Nano Science Technology; Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD); 111 ProjectMinistry of Education, China - 111 Project; German Research FoundationGerman Research Foundation (DFG) [392178740, 426888090]
  • Selective C(sp(3))-H activation is of fundamental importance in processing alkane feedstocks to produce high-value-added chemical products. By virtue of an on-surface synthesis strategy, we report selective cascade dehydrogenation of n-alkane molecules under surface constraints, which yields monodispersed all-trans conjugated polyenes with unprecedented length controllability. We are also able to demonstrate the generality of this concept for alkyl-substituted molecules with programmable lengths and diverse functionalities, and more importantly its promising potential in molecular wiring.

Subject headings and genre

Added entries (persons, corporate bodies, meetings, titles ...)

  • Niu, KaifengLinköpings universitet,Tunnfilmsfysik,Tekniska fakulteten,Soochow Univ, Peoples R China(Swepub:liu)kaini78 (author)
  • Zhang, JunjieSoochow Univ, Peoples R China (author)
  • Yu, XiaojuanKarlsruhe Inst Technol, Germany (author)
  • Zhang, HaimingSoochow Univ, Peoples R China (author)
  • Wang, YueminKarlsruhe Inst Technol, Germany (author)
  • Guo, QingSouthern Univ Sci & Technol, Peoples R China (author)
  • Wang, PengdongChinese Acad Sci, Peoples R China (author)
  • Li, FangsenChinese Acad Sci, Peoples R China (author)
  • Hao, ZhengmingSoochow Univ, Peoples R China (author)
  • Xu, ChaojieSoochow Univ, Peoples R China (author)
  • Tang, YanningSoochow Univ, Peoples R China (author)
  • Xu, ZhichaoSoochow Univ, Peoples R China (author)
  • Lu, ShuaiSoochow Univ, Peoples R China; Chinese Acad Sci, Peoples R China (author)
  • Liu, PengSouthern Univ Sci & Technol, Peoples R China (author)
  • Xue, GuiguSouthern Univ Sci & Technol, Peoples R China (author)
  • Wei, YenTsinghua Univ, Peoples R China (author)
  • Chi, LifengSoochow Univ, Peoples R China (author)
  • Soochow Univ, Peoples R ChinaTunnfilmsfysik (creator_code:org_t)

Related titles

  • In:National Science Review: Oxford University Press8:102095-51382053-714X

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