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- Cai, Weidong,1991-Linköpings universitet,Elektroniska och fotoniska material,Tekniska fakulteten (author)
Chirality Induced Crystal Structural Difference in Metal Halide Composites
- Article/chapterEnglish2022
Publisher, publication year, extent ...
- 2022-05-27
- Wiley-V C H Verlag GMBH,2022
- electronicrdacarrier
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- LIBRIS-ID:oai:DiVA.org:liu-185587
- https://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-185587URI
- https://doi.org/10.1002/adom.202102140DOI
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- Language:English
- Summary in:English
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- Funding Agencies|Knut and Alice Wallenberg Foundation [KAW 2019.0082]; Swedish Government Strategic Research Area in Materials Science on Functional Materials at Linkoping University [2009-00971]; China Scholarship Council (CSC)
- Incorporating chiral organic compounds into metal halide frames is a common and useful method to introduce chirality in metal halide composites. The structures of resulting racemic and chiral composites are usually considered to be nearly identical owing to similar chemical bonding. In this work, by incorporating chiral MBABr (bromide methylbenzylamine) into an inorganic frame, a significant crystallization difference between the resulting racemic and chiral metal halide composites is observed, as confirmed by both structural and spectroscopic measurements. In addition, the structural transformation in the chiral composites can also be induced by moisture, ascribed to the asymmetric hydrogen bonding in chiral materials. These results provide new insights for the future synthesis of chiral materials and open up new possibilities to advance the materials functionalities.
Subject headings and genre
- NATURVETENSKAP Kemi Organisk kemi hsv//swe
- NATURAL SCIENCES Chemical Sciences Organic Chemistry hsv//eng
- asymmetric hydrogen bonding; chirality; crystal structure difference; lead-free; moisture
Added entries (persons, corporate bodies, meetings, titles ...)
- Qin, JiajunLinköpings universitet,Elektroniska och fotoniska material,Tekniska fakulteten(Swepub:liu)jiaqi14 (author)
- Pang, TiqiangXidian Univ, Peoples R China (author)
- Cai, XinyiLinköpings universitet,Elektroniska och fotoniska material,Tekniska fakulteten(Swepub:liu)xinca37 (author)
- Jia, RenxuXidian Univ, Peoples R China (author)
- Gao, Feng,1981-Linköpings universitet,Elektroniska och fotoniska material,Tekniska fakulteten(Swepub:liu)fenga88 (author)
- Linköpings universitetElektroniska och fotoniska material (creator_code:org_t)
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- In:Advanced Optical Materials: Wiley-V C H Verlag GMBH10:162162-75682195-1071
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