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Bottom-up, scalable...
Bottom-up, scalable synthesis of anatase nanofilament-based two-dimensional titanium carbo-oxide flakes
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- Badr, Hussein O. (author)
- Drexel Univ, PA 19104 USA
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- El-Melegy, Tarek (author)
- Drexel Univ, PA 19104 USA
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- Carey, Michael (author)
- Drexel Univ, PA 19104 USA
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- Natu, Varun (author)
- Drexel Univ, PA 19104 USA
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- Hassig, Mary Q. (author)
- Drexel Univ, PA 19104 USA
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- Johnson, Craig (author)
- Drexel Univ, PA 19104 USA
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- Qian, Qian (author)
- Drexel Univ, PA 19104 USA
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- Li, Christopher Y. (author)
- Drexel Univ, PA 19104 USA
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- Kushnir, Kateryna (author)
- Worcester Polytech Inst, MA 01609 USA
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- Colin-Ulloa, Erika (author)
- Worcester Polytech Inst, MA 01609 USA
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- Titova, Lyubov V (author)
- Worcester Polytech Inst, MA 01609 USA
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- Martin, Julia L. (author)
- Worcester Polytech Inst, MA 01609 USA
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- Grimm, Ronald L. (author)
- Worcester Polytech Inst, MA 01609 USA
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- Pai, Rahul (author)
- Drexel Univ, PA 19104 USA
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- Kalra, Vibha (author)
- Drexel Univ, PA 19104 USA
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- Karmakar, Avishek (author)
- Drexel Univ, PA 19104 USA
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- Ruffino, Anthony (author)
- Drexel Univ, PA 19104 USA
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- Masiuk, Stefan (author)
- Drexel Univ, PA 19104 USA
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- Liang, Kun (author)
- Tulane Univ, LA 70118 USA
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- Naguib, Michael (author)
- Tulane Univ, LA 70118 USA
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- Wilson, Olivia (author)
- Drexel Univ, PA 19104 USA
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- Magenau, Andrew (author)
- Drexel Univ, PA 19104 USA
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- Montazeri, Kiana (author)
- Drexel Univ, PA 19104 USA
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- Zhu, Yucheng (author)
- Drexel Univ, PA 19104 USA
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- Cheng, Hao (author)
- Drexel Univ, PA 19104 USA
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- Torita, Takeshi (author)
- Murata Mfg Co Ltd, Japan
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- Koyanagi, Masashi (author)
- Murata Mfg Co Ltd, Japan
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- Yanagimachi, Akimaro (author)
- Murata Mfg Co Ltd, Japan
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- Ouisse, Thierry (author)
- Univ Grenoble Alpes, France
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- Barbier, Maxime (author)
- Univ Grenoble Alpes, France; European Synchrotron Radiat Facil ESRF, France
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- Wilhelm, Fabrice (author)
- European Synchrotron Radiat Facil ESRF, France
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- Rogalev, Andrei (author)
- European Synchrotron Radiat Facil ESRF, France
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- Björk, Jonas (author)
- Linköpings universitet,Tunnfilmsfysik,Tekniska fakulteten
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- Persson, Per O A (author)
- Linköpings universitet,Tunnfilmsfysik,Tekniska fakulteten
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- Rosén, Johanna (author)
- Linköpings universitet,Tunnfilmsfysik,Tekniska fakulteten
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- Hu, Yong-Jie (author)
- Drexel Univ, PA 19104 USA
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- Barsoum, Michel (author)
- Linköpings universitet,Tunnfilmsfysik,Tekniska fakulteten,Drexel Univ, PA 19104 USA
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(creator_code:org_t)
- ELSEVIER SCI LTD, 2022
- 2022
- English.
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In: Materials Today. - : ELSEVIER SCI LTD. - 1369-7021 .- 1873-4103. ; 54
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
Close
- Two-dimensional (2D) materials offer advantages that their 3D counterparts do not. The conventional method for the bulk synthesis of 2D materials has predominantly been through etching layered solids. Herein, we convert - through a bottom-up approach - 10 binary and ternary titanium carbides, nitrides, borides, phosphides, and silicides into 2D flakes by immersing them in a tetramethylammonium hydroxide solution at temperatures in the 25-85 degrees C range. Based on X-ray diffraction, density functional theory, X-ray photoelectron, electron energy loss, Raman, X-ray absorption near edge structure spectroscopies, transmission and scanning electron microscope images and selected area diffraction, we conclude that the resulting flakes are carbon containing anatase-based layers that are, in turn, comprised of approximate to 6 x 10 angstrom(2) nanofilaments in cross-section some of which are few microns long. Electrodes made from some of these films performed well in lithium-ion and lithium-sulphur systems. These materials also reduce the viability of cancer cells thus showing potential in biomedical applications. Synthesizing 2D materials, at near ambient conditions, with non-layered, inexpensive, green precursors (e.g., TiC) is paradigm shifting and will undoubtedly open new and exciting avenues of research and applications.
Subject headings
- NATURVETENSKAP -- Kemi -- Materialkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Materials Chemistry (hsv//eng)
Keyword
- Layered solids; 2D flakes; Nanofilaments; Self-assembly; Organic salts; Bottom-up; Energy storage
Publication and Content Type
- ref (subject category)
- art (subject category)
Find in a library
To the university's database
- By the author/editor
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Badr, Hussein O.
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El-Melegy, Tarek
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Carey, Michael
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Natu, Varun
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Hassig, Mary Q.
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Johnson, Craig
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show more...
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Qian, Qian
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Li, Christopher ...
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Kushnir, Kateryn ...
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Colin-Ulloa, Eri ...
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Titova, Lyubov V
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Martin, Julia L.
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Grimm, Ronald L.
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Pai, Rahul
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Kalra, Vibha
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Karmakar, Avishe ...
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Ruffino, Anthony
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Masiuk, Stefan
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Liang, Kun
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Naguib, Michael
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Wilson, Olivia
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Magenau, Andrew
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Montazeri, Kiana
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Zhu, Yucheng
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Cheng, Hao
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Torita, Takeshi
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Koyanagi, Masash ...
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Yanagimachi, Aki ...
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Ouisse, Thierry
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Barbier, Maxime
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Wilhelm, Fabrice
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Rogalev, Andrei
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Björk, Jonas
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Persson, Per O A
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Rosén, Johanna
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Hu, Yong-Jie
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Barsoum, Michel
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- About the subject
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Chemical Science ...
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and Materials Chemis ...
- Articles in the publication
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Materials Today
- By the university
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Linköping University