Search: onr:"swepub:oai:DiVA.org:liu-50124" >
Vibronic coupling i...
Vibronic coupling in the ground and excited states of oligoacene cations
-
- Sanchez-Carrera, R.S. (author)
- Sánchez-Carrera, R.S., School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, GA 30332-0400
-
- Coropceanu, V. (author)
- School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, GA 30332-0400
-
- Da, Silva Filho D.A. (author)
- Da Silva Filho, D.A., School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, GA 30332-0400
-
show more...
-
- Friedlein, Rainer (author)
- Linköpings universitet,Tekniska högskolan,Ytors Fysik och Kemi
-
- Osikowicz, Wojciech (author)
- Linköpings universitet,Tekniska högskolan,Ytors Fysik och Kemi
-
Murdey, R. (author)
-
Suess, C. (author)
-
- Salaneck, William R (author)
- Linköpings universitet,Tekniska högskolan,Ytors Fysik och Kemi
-
- Bredas, J.-L. (author)
- Brédas, J.-L., School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, GA 30332-0400
-
show less...
-
Sánchez-Carrera, RS., School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, GA 30332-0400 School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, GA 30332-0400 (creator_code:org_t)
- 2006-06-13
- 2006
- English.
-
In: Journal of Physical Chemistry B. - : American Chemical Society (ACS). - 1520-6106 .- 1520-5207. ; 110:38, s. 18904-18911
- Related links:
-
https://urn.kb.se/re...
-
show more...
-
https://doi.org/10.1...
-
show less...
Abstract
Subject headings
Close
- The vibrational coupling in the ground and excited states of positively charged naphthalene, anthracene, tetracene, and pentacene molecules is studied on the basis of a joint experimental and theoretical study of ionization spectra using high-resolution gas-phase photoelectron spectroscopy and first-principles correlated quantum-mechanical calculations. Our theoretical and experimental results reveal that, while the main contribution to relaxation energy in the ground state of oligoacene systems comes from high-energy vibrations, the excited-state relaxation energies show a significant redistribution toward lower-frequency vibrations. A direct correlation is found between the nature of the vibronic interaction and the pattern of the electronic state structure. © 2006 American Chemical Society.
Keyword
- TECHNOLOGY
- TEKNIKVETENSKAP
Publication and Content Type
- ref (subject category)
- art (subject category)
Find in a library
To the university's database