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Influence of pH, Precursor Concentration, Growth Time, and Temperature on the Morphology of ZnO Nanostructures Grown by the Hydrothermal Method

Amin, Gul (author)
Linköpings universitet,Fysik och elektroteknik,Tekniska högskolan,Fysikalisk elektronik och Nanoteknologi / Physical Electronics and nanotechnology
Asif, Muhammad (author)
Linköpings universitet,Fysik och elektroteknik,Tekniska högskolan,Fysikalisk elektronik och Nanoteknologi / Physical Electronics and nanotechnology
Zainelabdin, Ahmed (author)
Linköpings universitet,Fysik och elektroteknik,Tekniska högskolan,Fysikalisk elektronik och Nanoteknologi / Physical Electronics and nanotechnology
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Zaman, Siama (author)
Linköpings universitet,Fysik och elektroteknik,Tekniska högskolan,Fysikalisk elektronik och Nanoteknologi / Physical Electronics and nanotechnology
Nur, Omer (author)
Linköpings universitet,Fysik och elektroteknik,Tekniska högskolan,Fysikalisk elektronik och Nanoteknologi / Physical Electronics and nanotechnology
Willander, Magnus (author)
Linköpings universitet,Fysik och elektroteknik,Tekniska högskolan,Fysikalisk elektronik och Nanoteknologi / Physical Electronics and nanotechnology
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 (creator_code:org_t)
NY, USA : Hindawi Publishing Corporation, 2011
2011
English.
In: Journal of Nanomaterials. - NY, USA : Hindawi Publishing Corporation. - 1687-4110 .- 1687-4129. ; :269692
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • We investigated the influence of the pH value, precursor concentration (C), growth time and temperature on the morphology of zinc oxide (ZnO) nanostructures. The pH of the starting solution was varied from1.8 to 12.5. It was found that the final pH reaches an inherent value of 6.6 independently of the initial pH solution. Various ZnO structures of nanotetrapod-like, flower-like, and urchin-like morphology were obtained at alkaline pH (8 to 12.5) whereas for pH solution lower than 8 rod-like nanostructures occurred. Moreover, we observed the erosion of the nanorods for a pH value less than 4.6. By changing the concentrations the density and size were also varied. On going from a high (C > 400mM) to lower (C < 25mM) C, the resulted ZnO nanostructures change from a film to nanorods (NRs) and finally nanowires (NWs). It was also found that the length and diameter of ZnO NRs follow a linear relation with time up to 10 hours, above which no further increase was observed. Finally the effect of growth temperature was seen as an influence on the aspect ratio.

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