SwePub
Sök i LIBRIS databas

  Extended search

onr:"swepub:oai:DiVA.org:liu-78520"
 

Search: onr:"swepub:oai:DiVA.org:liu-78520" > Hydrogen and Coordi...

  • 1 of 1
  • Previous record
  • Next record
  •    To hitlist

Hydrogen and Coordination Bonding Supramolecular Structures of Trimesic Acid on Cu(110)

Classen, Thomas (author)
Max-Planck-Institut für Festkörperforschung, Stuttgart, Germany
Lingenfelder, Magali (author)
Max-Planck-Institut für Festkörperforschung, Stuttgart, Germany
Wang, Yeliang (author)
Max-Planck-Institut für Festkörperforschung, Stuttgart, Germany
show more...
Chopra, Rishav (author)
Max-Planck-Institut für Festkörperforschung, Stuttgart, Germany
Virojanadara, Chariya (author)
Max-Planck-Institut für Festkörperforschung, Stuttgart, Germany
Starke, Ulrich (author)
Max-Planck-Institut für Festkörperforschung, Stuttgart, Germany
Constantini, Giovanni (author)
Max-Planck-Institut für Festkörperforschung, Stuttgart, Germany
Kern, Klaus (author)
Max-Planck-Institut für Festkörperforschung, Stuttgart, Germany
Fratesi, G. (author)
INFM-CNR DEMOCRITOS Theory@Elettra group and SISSA Scuola Internazionale Superiore di Studi Avanzati, Trieste, Italy
Fabris, S. (author)
INFM-CNR DEMOCRITOS Theory@Elettra group and SISSA Scuola Internazionale Superiore di Studi Avanzati, Trieste, Italy
Gironcoli, S. (author)
INFM-CNR DEMOCRITOS Theory@Elettra group and SISSA Scuola Internazionale Superiore di Studi Avanzati, Trieste, Italy
Baroni, S. (author)
INFM-CNR DEMOCRITOS Theory@Elettra group and SISSA Scuola Internazionale Superiore di Studi Avanzati, Trieste, Italy
Haq, S. (author)
Surface Science Research Centre, University of Liverpool, U.K.
Raval, R. (author)
Surface Science Research Centre, University of Liverpool, U.K.
show less...
 (creator_code:org_t)
2007-11-10
2007
English.
In: Journal of Physical Chemistry A. - : American Chemical Society (ACS). - 1089-5639 .- 1520-5215. ; 111:49, s. 12589-12603
Related links:
http://www.fkf.mpg.d...
show more...
https://urn.kb.se/re...
https://doi.org/10.1...
show less...
  • Journal article (peer-reviewed)
Abstract Subject headings
Close  
  • The adsorption of trimesic acid (TMA) on Cu(110) has been studied in the temperature range between 130 and 550 K and for coverages up to one monolayer. We combine scanning tunneling microscopy (STM), low-energy electron diffraction (LEED), reflection absorption infrared spectroscopy (RAIRS), X-ray photoemission spectroscopy (XPS), and density functional theory (DFT) calculations to produce a detailed adsorption phase diagram for the TMA/Cu(110) system as a function of the molecular coverage and the substrate temperature. We identify a quite complex set of adsorption phases, which are determined by the interplay between the extent of deprotonation, the intermolecular bonding, and the overall energy minimization. For temperatures up to 280 K, TMA molecules are only partly deprotonated and form hydrogen-bonded structures, which locally exhibit organizational chirality. Above this threshold, the molecules deprotonate completely and form supramolecular metal−organic structures with Cu substrate adatoms. These structures exist in the form of single and double coordination chains, with the molecular coverage driving distinct phase transitions.

Publication and Content Type

ref (subject category)
art (subject category)

Find in a library

To the university's database

  • 1 of 1
  • Previous record
  • Next record
  •    To hitlist

Kungliga biblioteket hanterar dina personuppgifter i enlighet med EU:s dataskyddsförordning (2018), GDPR. Läs mer om hur det funkar här.
Så här hanterar KB dina uppgifter vid användning av denna tjänst.

 
pil uppåt Close

Copy and save the link in order to return to this view