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Synthesis, crystal ...
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Tian, Yu-pengDepartment of Chemistry, Anhui University, China
(author)
Synthesis, crystal structure and NLO properties of a novel ruthenium(II) complex with unusual coordination mode
- Article/chapterEnglish2005
Publisher, publication year, extent ...
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2014-01-07
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Kluwer Academic Publishers,2005
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printrdacarrier
Numbers
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LIBRIS-ID:oai:DiVA.org:liu-90623
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https://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-90623URI
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https://doi.org/10.1007/s11243-005-4825-5DOI
Supplementary language notes
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Language:English
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Summary in:English
Part of subdatabase
Classification
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Subject category:ref swepub-contenttype
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Subject category:art swepub-publicationtype
Notes
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A new Schiff base 4-[N-hydroxyethyl-N-(methyl)amino]benzaldehyde S-methyl dithiocarbazate (HL, where H is a dissociable proton) and the ruthenium complex [Ru(bpy)2L]PF6 (bpy = 2,2′-bipyridine) have been synthesized. The structural determinations of the ligand and its ruthenium complex, by X-ray crystallography, show that the ligand is coordinated as a monoanionic bidentate N, S-donor, forming a four-member chelate ring with a bite angle of 65.91°. The complex shows intense MLCT transitions in the visible region. Fluorescent and electrochemical properties have been also studied. The complex in DMF solution exhibited a strong two-photon absorption (t.p.a.) at 532 nm nanosecond laser pulses. The t.p.a. coefficient β, t.p.a. cross-section σ and the third-order optical nonlinearity χ(3) of the complex and the ligand have been determined by the Z-scan technique.
Added entries (persons, corporate bodies, meetings, titles ...)
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Zhang, Ming-liangDepartment of Chemistry, Anhui University, China
(author)
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Hu, Zhang-JunDepartment of Chemistry, Anhui University, China
(author)
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Hu, Han-meiDepartment of Chemistry, Anhui University, China
(author)
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Wu, Jie-YingDepartment of Chemistry, Anhui University, China
(author)
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Zhang, XuanjunDepartment of Chemistry, Anhui University, China
(author)
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Zhang, Sheng-YIDepartment of Chemistry, Anhui University, China
(author)
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Tao, XutangState Key Laboratory of Crystal Materials, Shandong University, China
(author)
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Jiang, MinhuaState Key Laboratory of Crystal Materials, Shandong University, China
(author)
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Chen, He-pingDepartment of Physics, Anhui University, China
(author)
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Chantrapromma, SuchadaCrystallography Unit, School of Physics, Universiti Sain Malaysia
(author)
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Fun, Hoong-KunCrystallography Unit, School of Physics, Universiti Sain Malaysia
(author)
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Department of Chemistry, Anhui University, ChinaState Key Laboratory of Crystal Materials, Shandong University, China
(creator_code:org_t)
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In:Transition metal chemistry (Weinheim): Kluwer Academic Publishers30:7, s. 778-7850340-42851572-901X
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