Inelastic scattering and satellite fine structure in the high-resolution uv photoelectron spectrum of CS2

• The outer valence region in CS2 has been studied by high-resolution UV photpelectron Spectroscopy. The spectra reveal detailed vibrational structure in the X 2Πg, A 2Πu, B 2Σ+u and C 2Σ+g bands. Some of the fine-structure peaks in the X B and C bands are shown to be pressure-dependent. The reason for the pressure dependence is assumed to be inelastic scattering of electrons emitted in the adiabatic transitions. It is established that the two CI satellite bands present in the He(I)-excited spectrum contain vibrational structure. 

Subject headings

NATURVETENSKAP  -- Fysik (hsv//swe)

NATURAL SCIENCES  -- Physical Sciences (hsv//eng)

Keyword

Physics

Fysik

Physics

Fysik

Publication and Content Type

ref (subject category)

art (subject category)